Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 24, Problem 33P
Interpretation Introduction

Interpretation:

The product obtained in the reduction reaction of α-ketoglutarate by a mutated form of isocitratedehydrogenase should be drawn.

Concept Introduction:

Glycolysis: It is pathway which describes conversion of one molecule of glucose into two molecules of pyruvate.  The series involves 10 reactions.

NAD+Molecule: It is the oxidized form of Nicotinamide adenine dinucleotide (NAD) which exists in all cells and needed for activation of enzymes.

NADHmolecule: It is coenzyme which gets oxidized on reducing another compound. The oxidized form of NADHisNAD+.

Citric acid cycle: The cycle in which acetyl group of each molecule of acetyl-CoA is converted into two molecules of CO2  It is a series of eight reactions.

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In the citric acid cycle, a - ketoglutarate dehydrogenase catalyzes the reaction from a - ketoglutarate to Succinyl CoA. Given this reaction, calculate for the enthalpy of formation of the product using (a) Hess's Law, (b) standard enthalpies of formation and (c) mean bond enthalpies. Show your complete solution. COA-S OOC CH2 CH2 + NAD++ COA + CO2 + NADH CH2 a-ketoglutarate CH2 dehydrogenase COO a-ketoglutarate COO Succinyl CoA
Please detail the chemical reaction catalyzed by alcohol dehydrogenase (ADH). (Provide details not just the chemicals involved)
The rate-limiting step is a metabolic pathway is the slowest step which determines the overall rate of the other reactions in the pathway. In glycolysis, the rate limiting step is a phosphorylation reaction where phosphofructokinase (PFK-1) catalyzes the reaction fructose-6-bisphosphate -> fructose-1,6-bisphosphate, the same step in gluconeogenesis. Select one: The statement is FALSE. The statement is TRUE.

Chapter 24 Solutions

Organic Chemistry (8th Edition)

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