Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Question
Chapter 24.5, Problem 1LTS
Interpretation Introduction
Interpretation:
The cyclic hemiacetal formed for the given hydroxyaldehyde in acidic condition should be drawn.
Concept introduction:
- Hemiacetal are formed for the compound having both hydroxyl group and
aldehyde group in acidic condition. - The –OH group of compound attacks the carbonyl group of the same compound, thereby a ring is formed by the carbon atoms and oxygen atom of –OH group with incorporating into the ring.
To determine: the size of the ring (hemiacetal) formed by the given molecule.
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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions. Assume all reagents are in excess unless otherwise indicated.
Chapter 24 Solutions
Organic Chemistry, Binder Ready Version
Ch. 24.2 - Prob. 1CCCh. 24.2 - Prob. 2CCCh. 24.2 - Prob. 3CCCh. 24.2 - Prob. 4CCCh. 24.2 - Prob. 5CCCh. 24.2 - Prob. 6CCCh. 24.4 - Prob. 7CCCh. 24.4 - Prob. 8CCCh. 24.5 - Prob. 1LTSCh. 24.5 - Prob. 9PTS
Ch. 24.5 - Prob. 10ATSCh. 24.5 - Prob. 11ATSCh. 24.5 - Prob. 2LTSCh. 24.5 - Prob. 12LTSCh. 24.5 - Prob. 13ATSCh. 24.5 - Prob. 14ATSCh. 24.5 - Prob. 15ATSCh. 24.5 - Prob. 3LTSCh. 24.5 - Prob. 16PTSCh. 24.5 - Prob. 17ATSCh. 24.5 - Prob. 18ATSCh. 24.5 - Prob. 19CCCh. 24.5 - Prob. 20CCCh. 24.5 - Prob. 21CCCh. 24.5 - Prob. 22CCCh. 24.6 - Prob. 23CCCh. 24.6 - Prob. 24CCCh. 24.6 - Prob. 25CCCh. 24.6 - Prob. 26CCCh. 24.6 - Prob. 27CCCh. 24.6 - Prob. 28CCCh. 24.6 - Prob. 29CCCh. 24.6 - Prob. 30CCCh. 24.6 - Prob. 4LTSCh. 24.6 - Prob. 31PTSCh. 24.6 - Prob. 32ATSCh. 24.6 - Prob. 33ATSCh. 24.6 - Prob. 34CCCh. 24.6 - Prob. 35CCCh. 24.6 - Prob. 36CCCh. 24.6 - Prob. 37CCCh. 24.6 - Prob. 38CCCh. 24.7 - Prob. 5LTSCh. 24.7 - Prob. 39PTSCh. 24.7 - Prob. 40ATSCh. 24.7 - Prob. 41CCCh. 24 - Prob. 42PPCh. 24 - Prob. 43PPCh. 24 - Prob. 44PPCh. 24 - Prob. 45PPCh. 24 - Prob. 46PPCh. 24 - Prob. 47PPCh. 24 - Prob. 48PPCh. 24 - Prob. 49PPCh. 24 - Prob. 50PPCh. 24 - Prob. 51PPCh. 24 - Prob. 52PPCh. 24 - Prob. 53PPCh. 24 - Prob. 54PPCh. 24 - Prob. 55PPCh. 24 - Prob. 56PPCh. 24 - Prob. 57PPCh. 24 - Prob. 58PPCh. 24 - Prob. 59PPCh. 24 - Prob. 60PPCh. 24 - Prob. 61PPCh. 24 - Prob. 62PPCh. 24 - Prob. 63PPCh. 24 - Prob. 64PPCh. 24 - Prob. 65PPCh. 24 - Prob. 66PPCh. 24 - Prob. 67PPCh. 24 - Prob. 68PPCh. 24 - Prob. 69PPCh. 24 - Prob. 70PPCh. 24 - Prob. 71PPCh. 24 - Prob. 72PPCh. 24 - Prob. 73PPCh. 24 - Prob. 74PPCh. 24 - Prob. 75PPCh. 24 - Prob. 76PPCh. 24 - Prob. 77PPCh. 24 - Prob. 78PPCh. 24 - Prob. 79PPCh. 24 - Prob. 80PPCh. 24 - Prob. 81IPCh. 24 - Prob. 82IPCh. 24 - Prob. 83IPCh. 24 - Prob. 84IP
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