Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 24, Problem 24.33P

(a)

Interpretation Introduction

Interpretation:

The product of given alkene metathesis reaction using a Ru‑nucleophilic carbene catalyst has to be predicted.

Organic Chemistry, Chapter 24, Problem 24.33P , additional homework tip  1

Concept Introduction:

Alkene metathesis:

An organometallic catalyzed reaction in which two alkenes exchange carbon atoms of their double bonds are said to be Alkene metathesis reaction.  Two alkenes are in same molecule and the product is a cycloalkene and ring closing occurs.  The catalyst used is Ru‑nucleophilic carbene complex.

Example:

Organic Chemistry, Chapter 24, Problem 24.33P , additional homework tip  2

(b)

Interpretation Introduction

Interpretation:

The product of given alkene metathesis reaction using a Ru‑nucleophilic carbene catalyst has to be predicted.

Organic Chemistry, Chapter 24, Problem 24.33P , additional homework tip  3

Concept Introduction:

Alkene metathesis:

An organometallic catalyzed reaction in which two alkenes exchange carbon atoms of their double bonds are said to be Alkene metathesis reaction.  Two alkenes are in same molecule and the product is a cycloalkene and ring closing occurs.  The catalyst used is Ru‑nucleophilic carbene complex.

Example:

Organic Chemistry, Chapter 24, Problem 24.33P , additional homework tip  4

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Finish the indicated reaction by filling in and starting materials, reagents or products as needed 
True or False Considering that two carbon chains have equal number of carbons, but one has Fluorine and the other has Iodine, the one with iodine will have a higher boiling point. Mild oxidation of alkenes results to similar product as that of nucleophilic addition of water to aldehydes.
4) Draw all of the possible alkene products from the following reaction. Indicate in what proportions these alkenes would be produced relative to one another. HO H₂SO4 Reflux
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