(a)
Interpretation: The product that is formed by the intramolecular aldol reaction of the given dicarbonyl compound followed by dehydration is to be drawn.
Concept introduction: The aldol reaction that takes place within the same molecule in the presence of strong base is known as intramolecular aldol reactions. This reaction generally takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate ion that acts as a nucleophile and the carbonyl carbon of the second carbonyl group acts as an electrophile.
(b)
Interpretation: The product that is formed by the intramolecular aldol reaction of the given dicarbonyl compound followed by dehydration is to be drawn.
Concept introduction: The aldol reaction that takes place within the same molecule in the presence of strong base is known as intramolecular aldol reactions. This reaction generally takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate ion that acts as a nucleophile and the carbonyl carbon of the second carbonyl group acts as an electrophile.
(c)
Interpretation: The product that is formed by the intramolecular aldol reaction of the given dicarbonyl compound followed by dehydration is to be drawn.
Concept introduction: The aldol reaction that takes place within the same molecule in the presence of strong base is known as intramolecular aldol reactions. This reaction generally takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate ion that acts as a nucleophile and the carbonyl carbon of the second carbonyl group acts as an electrophile.
Trending nowThis is a popular solution!
Chapter 24 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
- Select the carbonyl compound which can form only a single enol via tautomerization. A. B. H C. D.arrow_forwardDraw the products obtained (including stereochemistry) when each compound is treated with LDA, followed by CH3I.arrow_forwardDraw the products formed (including stereoisomers) when each compound is reduced with NaBH4 in CH3OH.arrow_forward
- Devise a synthesis of each compound. You may use HC=CH, ethylene oxide, and alkyl halides as organic starting materials and any inorganic reagents.arrow_forwardDevise a synthesis of each compound from ethanol (CH3CH2OH) as the only source of carbon atoms. You may use any other organic or inorganic reagents you choose.arrow_forwardDraw enol tautomer(s) for each compound. Which carbonyl compound(s) favor the enol tautomer?arrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY