(a) Interpretation: The aldol product that formed by the given compound is to be drawn. Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry . In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β -hydroxyaldehyde or β -hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α − hydrogen atom to undergo aldol reaction.

Question

Want to see more full solutions like this?

Answer 1

Question

Chapter 24, Problem 24.1P

Interpretation Introduction

(a)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 1

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 2

Figure 1

In this aldol reaction, one equivalent of 2−phenylacetaldehyde is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 2−phenylacetaldehyde is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 3−hydroxy−2,4−diphenylbutanal.

Conclusion

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal.

Interpretation Introduction

(b)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 3

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 4

Figure 2

In this aldol reaction, one equivalent of 3,3−dimethylbutanal is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 3,3−dimethylbutanal is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Conclusion

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Interpretation Introduction

(c)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 5

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 6

Figure 3

In this aldol reaction, one equivalent of propane−2−one is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of propane−2−one is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 4−hydroxy−4−methylpentan−2−one.

Conclusion

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one.

Interpretation Introduction

(d)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 7

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 8

Figure 4

In this aldol reaction, one equivalent of cyclohexanone is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of cyclohexanone is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Conclusion

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Students have asked these similar questions

my ccc edu - Search X Quick Access X D2L Homepage - Spring 2025 x N Netflix X Dimensional Analysis - A x+ pp.aktiv.com Q ☆ X Question 59 of 70 The volume of 1 unit of plasma is 200.0 mL If the recommended dosage for adult patients is 10.0 mL per kg of body mass, how many units are needed for a patient with a body mass of 80.0 kg ? 80.0 kg 10.0 DAL 1 units X X 4.00 units 1 1 Jeg 200.0 DAL L 1 units X 200.0 mL = 4.00 units ADD FACTOR *( ) DELETE ANSWER RESET D 200.0 2.00 1.60 × 10³ 80.0 4.00 0.0400 0.250 10.0 8.00 & mL mL/kg kg units/mL L unit Q Search delete prt sc 111 110 19

Identify the starting material in the following reaction. Click the "draw structure" button to launch the drawing utility. draw structure ... [1] 0 3 C10H18 [2] CH3SCH3 H

In an equilibrium mixture of the formation of ammonia from nitrogen and hydrogen, it is found that PNH3 = 0.147 atm, PN2 = 1.41 atm and Pн2 = 6.00 atm. Evaluate Kp and Kc at 500 °C. 2 NH3 (g) N2 (g) + 3 H₂ (g) K₂ = (PN2)(PH2)³ = (1.41) (6.00)³ = 1.41 x 104

Answer 2

Question

Chapter 24, Problem 24.1P

Interpretation Introduction

(a)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 1

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 2

Figure 1

In this aldol reaction, one equivalent of 2−phenylacetaldehyde is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 2−phenylacetaldehyde is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 3−hydroxy−2,4−diphenylbutanal.

Conclusion

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal.

Interpretation Introduction

(b)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 3

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 4

Figure 2

In this aldol reaction, one equivalent of 3,3−dimethylbutanal is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 3,3−dimethylbutanal is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Conclusion

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Interpretation Introduction

(c)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 5

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 6

Figure 3

In this aldol reaction, one equivalent of propane−2−one is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of propane−2−one is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 4−hydroxy−4−methylpentan−2−one.

Conclusion

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one.

Interpretation Introduction

(d)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 7

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 8

Figure 4

In this aldol reaction, one equivalent of cyclohexanone is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of cyclohexanone is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Conclusion

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Question

Chapter 24, Problem 24.1P

Interpretation Introduction

(a)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 1

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 2

Figure 1

In this aldol reaction, one equivalent of 2−phenylacetaldehyde is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 2−phenylacetaldehyde is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 3−hydroxy−2,4−diphenylbutanal.

Conclusion

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal.

Interpretation Introduction

(b)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 3

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 4

Figure 2

In this aldol reaction, one equivalent of 3,3−dimethylbutanal is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 3,3−dimethylbutanal is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Conclusion

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Interpretation Introduction

(c)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 5

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 6

Figure 3

In this aldol reaction, one equivalent of propane−2−one is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of propane−2−one is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 4−hydroxy−4−methylpentan−2−one.

Conclusion

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one.

Interpretation Introduction

(d)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 7

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 8

Figure 4

In this aldol reaction, one equivalent of cyclohexanone is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of cyclohexanone is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Conclusion

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Chapter 24, Problem 24.1P

Interpretation Introduction

(a)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 1

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 2

Figure 1

In this aldol reaction, one equivalent of 2−phenylacetaldehyde is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 2−phenylacetaldehyde is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 3−hydroxy−2,4−diphenylbutanal.

Conclusion

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal.

Interpretation Introduction

(b)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 3

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 4

Figure 2

In this aldol reaction, one equivalent of 3,3−dimethylbutanal is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 3,3−dimethylbutanal is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Conclusion

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Interpretation Introduction

(c)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 5

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 6

Figure 3

In this aldol reaction, one equivalent of propane−2−one is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of propane−2−one is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 4−hydroxy−4−methylpentan−2−one.

Conclusion

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one.

Interpretation Introduction

(d)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 7

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 8

Figure 4

In this aldol reaction, one equivalent of cyclohexanone is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of cyclohexanone is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Conclusion

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 24, Problem 24.1P

Interpretation Introduction

(a)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 1

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 2

Figure 1

In this aldol reaction, one equivalent of 2−phenylacetaldehyde is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 2−phenylacetaldehyde is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 3−hydroxy−2,4−diphenylbutanal.

Conclusion

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal.

Interpretation Introduction

(b)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 3

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 4

Figure 2

In this aldol reaction, one equivalent of 3,3−dimethylbutanal is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 3,3−dimethylbutanal is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Conclusion

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Interpretation Introduction

(c)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 5

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 6

Figure 3

In this aldol reaction, one equivalent of propane−2−one is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of propane−2−one is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 4−hydroxy−4−methylpentan−2−one.

Conclusion

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one.

Interpretation Introduction

(d)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 7

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 8

Figure 4

In this aldol reaction, one equivalent of cyclohexanone is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of cyclohexanone is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Conclusion

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Answer 6

Chapter 24, Problem 24.1P

Interpretation Introduction

(a)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 1

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 2

Figure 1

In this aldol reaction, one equivalent of 2−phenylacetaldehyde is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 2−phenylacetaldehyde is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 3−hydroxy−2,4−diphenylbutanal.

Conclusion

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal.

Answer 7

Chapter 24, Problem 24.1P

Interpretation Introduction

(a)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Answer 8

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 1

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 2

Figure 1

In this aldol reaction, one equivalent of 2−phenylacetaldehyde is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 2−phenylacetaldehyde is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 3−hydroxy−2,4−diphenylbutanal.

Answer 13

Conclusion

The aldol product that formed by the given compound is 3−hydroxy−2,4−diphenylbutanal.

Answer 14

Interpretation Introduction

(b)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 3

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 4

Figure 2

In this aldol reaction, one equivalent of 3,3−dimethylbutanal is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 3,3−dimethylbutanal is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Conclusion

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Answer 15

Interpretation Introduction

(b)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Answer 16

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 3

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 4

Figure 2

In this aldol reaction, one equivalent of 3,3−dimethylbutanal is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of 3,3−dimethylbutanal is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Answer 21

Conclusion

The aldol product that formed by the given compound is 2−(tert−butyl)−3−hydroxy−5,5−dimethylhexanal.

Answer 22

Interpretation Introduction

(c)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 5

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 6

Figure 3

In this aldol reaction, one equivalent of propane−2−one is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of propane−2−one is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 4−hydroxy−4−methylpentan−2−one.

Conclusion

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one.

Answer 23

Interpretation Introduction

(c)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Answer 24

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 5

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 6

Figure 3

In this aldol reaction, one equivalent of propane−2−one is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of propane−2−one is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 4−hydroxy−4−methylpentan−2−one.

Answer 29

Conclusion

The aldol product that formed by the given compound is 4−hydroxy−4−methylpentan−2−one.

Answer 30

Interpretation Introduction

(d)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 7

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 8

Figure 4

In this aldol reaction, one equivalent of cyclohexanone is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of cyclohexanone is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Conclusion

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.

Answer 31

Interpretation Introduction

(d)

Interpretation: The aldol product that formed by the given compound is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone. It is necessary that the carbonyl compound must contain at least one α−hydrogen atom to undergo aldol reaction.

Answer 32

Expert Solution

Answer to Problem 24.1P

The aldol product that formed by the given compound is 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one as shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 7

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

The aldol product that formed by the given compound is shown below.

Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card, Chapter 24, Problem 24.1P , additional homework tip 8

Figure 4

In this aldol reaction, one equivalent of cyclohexanone is treated with strong base that results in the formation of resonance-stabilized enolate ion. The second equivalent of cyclohexanone is then reacts with enolate ion. After that, hydrolysis of the intermediate compound takes place that results the formation of the desired product, 1'−hydroxy−[1,1'−bi(cyclohexan)]−2−one.