
Concept explainers
a)
Interpretation:
The structure for trans-2-pentene has to be drawn.
Concept introduction:
- The longest continuous chain of carbon atoms is identified.
- The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
- While numbering the longest chain, the substituent should get least possible number.
- Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hypen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.
Geometric isomers of
Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.
Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.
b)
Interpretation:
The structure for 2-ethyl-1-butene has to be drawn.
Concept introduction:
IUPAC Nomenclature:
- The longest continuous chain of carbon atoms is identified.
- The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
- While numbering the longest chain, the substituent should get least possible number.
- Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.
c)
Interpretation:
The structure for 4-ethyl-trans-2-heptene has to be drawn.
Concept introduction:
IUPAC Nomenclature:
- The longest continuous chain of carbon atoms is identified.
- The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
- While numbering the longest chain, the substituent should get least possible number.
- Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.
Geometric isomers of Alkenes:
Cis-isomer: When two particular atoms (group of atoms) are adjacent to each other, the alkene is known as cis-isomer.
Trans-isomer: When two particular atoms (group of atoms) are across from each other, the alkene is known as cis-isomer.
d)
Interpretation:
The structure for 3-phenyl-butyne has to be drawn.
Concept introduction:
IUPAC Nomenclature:
- The longest continuous chain of carbon atoms is identified.
- The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.
- While numbering the longest chain, the substituent should get least possible number.
- Write the name of the compound; the parent name written as last part of the name by replacing ‘ane’ to ‘ene’. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

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Chapter 24 Solutions
CHEMISTRY (LOOSELEAF) >CUSTOM<
- Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.arrow_forwardе. Д CH3 D*, D20arrow_forwardC. NaOMe, Br Brarrow_forward
- Please predict the products for each of the following reactions: 1.03 2. H₂O NaNH, 1. n-BuLi 2. Mel A H₂ 10 9 0 H2SO4, H₂O HgSO4 Pd or Pt (catalyst) B 9 2 n-BuLi ♡ D2 (deuterium) Lindlar's Catalyst 1. NaNH2 2. EtBr Na, ND3 (deuterium) 2. H₂O2, NaOH 1. (Sia)2BH с Darrow_forwardin the scope of ontario SCH4U grade 12 course, please show ALL workarrow_forwardIs the chemical reaction CuCl42-(green) + 4H2O <==> Cu(H2O)42+(blue) + 4Cl- exothermic or endothermic?arrow_forward
- If we react tetraethoxypropane with hydrazine, what is the product obtained (explain its formula). State the reason why the corresponding dialdehyde is not used.arrow_forwarddrawing, no aiarrow_forwardIf CH3COCH2CH(OCH3)2 (4,4-dimethoxy-2-butanone) and hydrazine react, two isomeric products are formed. State their structure and which will be the majority.arrow_forward
- Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
