Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Question
Chapter 23, Problem 65PS
Interpretation Introduction
Interpretation:
To write the chemical equation for the synthesis of the polyacrylonitrile
Concept introduction:
polyacrylonitrile polymer is a syntehtic and semi crystalline polymer resin.It is also knon a Creslan 61.It is used to make carbon fibre and polyarylonitrile.It is a white solid.It does not melt under the normal conditions.
The structure of polyacrylonitrile polymer as shon below.
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(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
.
3°C
with
TH
12. (10pts total) Provide the major product for each reaction depicted below. If no reaction
occurs write NR. Assume heat dissipation is carefully controlled in the fluorine reaction.
3H
24 total (30)
24
21
2h
• 6H total
● 8H total
34
래
Br2
hv
major product
will be most
Substituted
12
hv
Br
NR
I too weak of a
participate in P-1
F₂
hv
Statistically
most favored
product will be
major
=
most subst =
thermo favored
hydrogen atom abstractor to
LL
F
Five chemistry project topic that does not involve practical
Chapter 23 Solutions
Chemistry & Chemical Reactivity
Ch. 23.2 - (a) Draw the nine isomers having the formula...Ch. 23.2 - Prob. 2CYUCh. 23.2 - There are 17 possible alkene isomers with the...Ch. 23.2 - Prob. 4CYUCh. 23.2 - Aniline, C6H5NH2, is the common name for...Ch. 23.2 - What is the systematic name for this alkane? (a)...Ch. 23.2 - Prob. 2RCCh. 23.2 - Prob. 3RCCh. 23.2 - Prob. 4RCCh. 23.2 - 5. How many isomers are possible for C6H4(CH3)Cl,...
Ch. 23.3 - Draw the structure of 1-butanol and alcohols that...Ch. 23.3 - Prob. 1RCCh. 23.3 - Prob. 2RCCh. 23.3 - What is the hybridization of nitrogen in...Ch. 23.3 - Prob. 4RCCh. 23.4 - (a) Name each of the following compounds and its...Ch. 23.4 - Prob. 1RCCh. 23.4 - Prob. 2RCCh. 23.4 - Prob. 3RCCh. 23.4 - Prob. 4RCCh. 23.4 - Prob. 1QCh. 23.4 - Prob. 2QCh. 23.4 - Prob. 3QCh. 23.5 - Kevlar is a well-known polymer that is now used to...Ch. 23.5 - Prob. 1QCh. 23.5 - Prob. 2QCh. 23.5 - Prob. 3QCh. 23.5 - Prob. 1RCCh. 23.5 - What is the atom economy for the reaction of...Ch. 23.5 - Prob. 5QCh. 23.5 - If drinking from a polycarbonate bottle, does a 15...Ch. 23.5 - Assume you weigh 156 lb. How much BPA do you...Ch. 23.5 - Prob. 8QCh. 23 - Prob. 1PSCh. 23 - What is the molecular formula for an alkane with...Ch. 23 - Prob. 3PSCh. 23 - Prob. 4PSCh. 23 - One of the structural isomers with the formula...Ch. 23 - Prob. 6PSCh. 23 - Prob. 7PSCh. 23 - Give the systematic name for the following alkane....Ch. 23 - Draw the structure of each of the following...Ch. 23 - Draw structures for the following compounds. (a)...Ch. 23 - Prob. 11PSCh. 23 - Prob. 12PSCh. 23 - Draw the structure of the chair form of...Ch. 23 - Prob. 14PSCh. 23 - Prob. 15PSCh. 23 - Prob. 16PSCh. 23 - Prob. 17PSCh. 23 - Prob. 18PSCh. 23 - Prob. 19PSCh. 23 - What structural requirement is necessary for an...Ch. 23 - A hydrocarbon with the formula C5H10, can be...Ch. 23 - Prob. 22PSCh. 23 - Prob. 23PSCh. 23 - Prob. 24PSCh. 23 - The compound 2-bromobutane is a product of...Ch. 23 - The compound 2,3-dibromo-2-methylhexane is formed...Ch. 23 - Prob. 27PSCh. 23 - Prob. 28PSCh. 23 - Prob. 29PSCh. 23 - Prob. 30PSCh. 23 - Prob. 31PSCh. 23 - Give the systematic name for each of the following...Ch. 23 - Prob. 33PSCh. 23 - Write an equation for the preparation of...Ch. 23 - Prob. 35PSCh. 23 - Prob. 36PSCh. 23 - Prob. 37PSCh. 23 - Prob. 38PSCh. 23 - Prob. 39PSCh. 23 - Name the following amines: (a) CH3CH2CH2NH2 (b)...Ch. 23 - Draw structural formulas for the four possible...Ch. 23 - Prob. 42PSCh. 23 - Prob. 43PSCh. 23 - Prob. 44PSCh. 23 - Prob. 45PSCh. 23 - Prob. 46PSCh. 23 - Prob. 47PSCh. 23 - Prob. 48PSCh. 23 - Prob. 49PSCh. 23 - Prob. 50PSCh. 23 - Give the structural formula and systematic name...Ch. 23 - Prob. 52PSCh. 23 - Prob. 53PSCh. 23 - Prob. 54PSCh. 23 - Prob. 55PSCh. 23 - Prob. 56PSCh. 23 - Prob. 57PSCh. 23 - Prob. 58PSCh. 23 - Prob. 59PSCh. 23 - Prob. 60PSCh. 23 - Identify the functional groups in the following...Ch. 23 - Prob. 62PSCh. 23 - Prob. 63PSCh. 23 - Prob. 64PSCh. 23 - Prob. 65PSCh. 23 - Prob. 66PSCh. 23 - Prob. 67GQCh. 23 - Prob. 68GQCh. 23 - Prob. 69GQCh. 23 - Prob. 70GQCh. 23 - Prob. 71GQCh. 23 - Prob. 72GQCh. 23 - Prob. 73GQCh. 23 - Write equations for the following reactions,...Ch. 23 - Prob. 75GQCh. 23 - Prob. 76GQCh. 23 - Draw the structure of each of the following...Ch. 23 - Prob. 78GQCh. 23 - Prob. 79GQCh. 23 - Draw structural formulas for possible isomers with...Ch. 23 - Prob. 81GQCh. 23 - Prob. 82GQCh. 23 - Prob. 83GQCh. 23 - Prob. 84GQCh. 23 - Prob. 85GQCh. 23 - Prob. 86GQCh. 23 - Draw the structure of glyceryl trilaurate, a fat....Ch. 23 - Prob. 88GQCh. 23 - Prob. 89GQCh. 23 - Prob. 90GQCh. 23 - Prob. 91GQCh. 23 - There are three ethers with the formula C4H10O....Ch. 23 - Review the opening photograph about chocolate...Ch. 23 - Prob. 94GQCh. 23 - Prob. 95ILCh. 23 - Prob. 96ILCh. 23 - Prob. 97ILCh. 23 - Prob. 98ILCh. 23 - Prob. 99ILCh. 23 - Prob. 100ILCh. 23 - Prob. 101ILCh. 23 - Prob. 102ILCh. 23 - Prob. 103ILCh. 23 - Prob. 104ILCh. 23 - Prob. 105ILCh. 23 - Prob. 106ILCh. 23 - Prob. 107SCQCh. 23 - Prob. 108SCQCh. 23 - Prob. 109SCQCh. 23 - Prob. 110SCQCh. 23 - Prob. 111SCQCh. 23 - Prob. 112SCQCh. 23 - Prob. 113SCQ
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