(a) Interpretation: The given reaction intermediates and curved arrow mechanism is to be explained. Concept Introduction: Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

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Answer 1

Question

Chapter 23, Problem 23.78AP

Interpretation Introduction

(a)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Interpretation Introduction

(b)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Intramolecular nucleophilic substitution reaction is that reaction in which both nucleophile and the electrophile are present in the same compound. The nucleophile attacks at the electrophilic centre and generally cyclization of the compound occurs. Sodium borohydride is a reducing agent which reduces the double bond present in the compound.

Interpretation Introduction

(c)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

In nucleophilic substitution reaction, the nucleophile which is the species having excess electrons attacks at the electron deficient electrophilic centre. There are two types of nucleophilic substitution reactions, SN1 or SN2 which are based on the reaction mechanism.

Interpretation Introduction

(d)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Acyl azide is heated in an inert solvent to form isocyanate with the loss of nitrogen as by product. This reaction is known as Curtius rearrangement reaction. Isocyanate product of the rearrangement can be converted into amine by hydration in either an acid or base.

Interpretation Introduction

(e)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

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What are the major products of the following reaction? Please provide a detailed explanation and a drawing to show how the reaction proceeds.

Answer 2

Question

Chapter 23, Problem 23.78AP

Interpretation Introduction

(a)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Interpretation Introduction

(b)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Intramolecular nucleophilic substitution reaction is that reaction in which both nucleophile and the electrophile are present in the same compound. The nucleophile attacks at the electrophilic centre and generally cyclization of the compound occurs. Sodium borohydride is a reducing agent which reduces the double bond present in the compound.

Interpretation Introduction

(c)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

In nucleophilic substitution reaction, the nucleophile which is the species having excess electrons attacks at the electron deficient electrophilic centre. There are two types of nucleophilic substitution reactions, SN1 or SN2 which are based on the reaction mechanism.

Interpretation Introduction

(d)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Acyl azide is heated in an inert solvent to form isocyanate with the loss of nitrogen as by product. This reaction is known as Curtius rearrangement reaction. Isocyanate product of the rearrangement can be converted into amine by hydration in either an acid or base.

Interpretation Introduction

(e)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

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Answer 3

Question

Chapter 23, Problem 23.78AP

Interpretation Introduction

(a)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Interpretation Introduction

(b)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Intramolecular nucleophilic substitution reaction is that reaction in which both nucleophile and the electrophile are present in the same compound. The nucleophile attacks at the electrophilic centre and generally cyclization of the compound occurs. Sodium borohydride is a reducing agent which reduces the double bond present in the compound.

Interpretation Introduction

(c)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

In nucleophilic substitution reaction, the nucleophile which is the species having excess electrons attacks at the electron deficient electrophilic centre. There are two types of nucleophilic substitution reactions, SN1 or SN2 which are based on the reaction mechanism.

Interpretation Introduction

(d)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Acyl azide is heated in an inert solvent to form isocyanate with the loss of nitrogen as by product. This reaction is known as Curtius rearrangement reaction. Isocyanate product of the rearrangement can be converted into amine by hydration in either an acid or base.

Interpretation Introduction

(e)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

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Answer 4

Question

Chapter 23, Problem 23.78AP

Interpretation Introduction

(a)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Interpretation Introduction

(b)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Intramolecular nucleophilic substitution reaction is that reaction in which both nucleophile and the electrophile are present in the same compound. The nucleophile attacks at the electrophilic centre and generally cyclization of the compound occurs. Sodium borohydride is a reducing agent which reduces the double bond present in the compound.

Interpretation Introduction

(c)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

In nucleophilic substitution reaction, the nucleophile which is the species having excess electrons attacks at the electron deficient electrophilic centre. There are two types of nucleophilic substitution reactions, SN1 or SN2 which are based on the reaction mechanism.

Interpretation Introduction

(d)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Acyl azide is heated in an inert solvent to form isocyanate with the loss of nitrogen as by product. This reaction is known as Curtius rearrangement reaction. Isocyanate product of the rearrangement can be converted into amine by hydration in either an acid or base.

Interpretation Introduction

(e)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

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Answer 5

Chapter 23, Problem 23.78AP

Interpretation Introduction

(a)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Interpretation Introduction

(b)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Intramolecular nucleophilic substitution reaction is that reaction in which both nucleophile and the electrophile are present in the same compound. The nucleophile attacks at the electrophilic centre and generally cyclization of the compound occurs. Sodium borohydride is a reducing agent which reduces the double bond present in the compound.

Interpretation Introduction

(c)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

In nucleophilic substitution reaction, the nucleophile which is the species having excess electrons attacks at the electron deficient electrophilic centre. There are two types of nucleophilic substitution reactions, SN1 or SN2 which are based on the reaction mechanism.

Interpretation Introduction

(d)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Acyl azide is heated in an inert solvent to form isocyanate with the loss of nitrogen as by product. This reaction is known as Curtius rearrangement reaction. Isocyanate product of the rearrangement can be converted into amine by hydration in either an acid or base.

Interpretation Introduction

(e)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Answer 6

Chapter 23, Problem 23.78AP

Interpretation Introduction

(a)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Answer 7

Chapter 23, Problem 23.78AP

Interpretation Introduction

(a)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Intramolecular nucleophilic substitution reaction is that reaction in which both nucleophile and the electrophile are present in the same compound. The nucleophile attacks at the electrophilic centre and generally cyclization of the compound occurs. Sodium borohydride is a reducing agent which reduces the double bond present in the compound.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Intramolecular nucleophilic substitution reaction is that reaction in which both nucleophile and the electrophile are present in the same compound. The nucleophile attacks at the electrophilic centre and generally cyclization of the compound occurs. Sodium borohydride is a reducing agent which reduces the double bond present in the compound.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

In nucleophilic substitution reaction, the nucleophile which is the species having excess electrons attacks at the electron deficient electrophilic centre. There are two types of nucleophilic substitution reactions, SN1 or SN2 which are based on the reaction mechanism.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

In nucleophilic substitution reaction, the nucleophile which is the species having excess electrons attacks at the electron deficient electrophilic centre. There are two types of nucleophilic substitution reactions, SN1 or SN2 which are based on the reaction mechanism.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Acyl azide is heated in an inert solvent to form isocyanate with the loss of nitrogen as by product. This reaction is known as Curtius rearrangement reaction. Isocyanate product of the rearrangement can be converted into amine by hydration in either an acid or base.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Acyl azide is heated in an inert solvent to form isocyanate with the loss of nitrogen as by product. This reaction is known as Curtius rearrangement reaction. Isocyanate product of the rearrangement can be converted into amine by hydration in either an acid or base.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The given reaction intermediates and curved arrow mechanism is to be explained.

Concept Introduction:

Diazotization reaction is reaction of aromatic amine compounds with nitrous acid. It is the conversion reaction of primary aromatic amine into its diazonium salt. Diazonium salt formed can be used in preparation of halogen compounds or in azo coupling reactions.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains that diazotization reaction is the conversion reaction of primary aromatic amine into its diazonium salt.

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Chapter 23 Solutions