(a) Interpretation: The structure of cocaine which is expected to present in 1 M aqueous HCl solution is to be predicted. Concept introduction: Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

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Answer 1

Question

Chapter 23, Problem 23.50AP

Interpretation Introduction

(a)

Interpretation:

The structure of cocaine which is expected to present in 1 M aqueous HCl solution is to be predicted.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Interpretation Introduction

(b)

Interpretation:

The products formed when cocaine is treated with an excess of aqueous NaOH and heat are to be predicted.

Concept introduction:

Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid. A hydrolysis reaction of ester carried out in a basic solution is known as saponification reaction.

Interpretation Introduction

(c)

Interpretation:

The products formed when cocaine is treated with an excess of concentrated aqueous HCl and heat is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 23, Problem 23.50AP

Interpretation Introduction

(a)

Interpretation:

The structure of cocaine which is expected to present in 1 M aqueous HCl solution is to be predicted.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Interpretation Introduction

(b)

Interpretation:

The products formed when cocaine is treated with an excess of aqueous NaOH and heat are to be predicted.

Concept introduction:

Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid. A hydrolysis reaction of ester carried out in a basic solution is known as saponification reaction.

Interpretation Introduction

(c)

Interpretation:

The products formed when cocaine is treated with an excess of concentrated aqueous HCl and heat is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

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Answer 3

Question

Chapter 23, Problem 23.50AP

Interpretation Introduction

(a)

Interpretation:

The structure of cocaine which is expected to present in 1 M aqueous HCl solution is to be predicted.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Interpretation Introduction

(b)

Interpretation:

The products formed when cocaine is treated with an excess of aqueous NaOH and heat are to be predicted.

Concept introduction:

Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid. A hydrolysis reaction of ester carried out in a basic solution is known as saponification reaction.

Interpretation Introduction

(c)

Interpretation:

The products formed when cocaine is treated with an excess of concentrated aqueous HCl and heat is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

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Answer 4

Question

Chapter 23, Problem 23.50AP

Interpretation Introduction

(a)

Interpretation:

The structure of cocaine which is expected to present in 1 M aqueous HCl solution is to be predicted.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Interpretation Introduction

(b)

Interpretation:

The products formed when cocaine is treated with an excess of aqueous NaOH and heat are to be predicted.

Concept introduction:

Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid. A hydrolysis reaction of ester carried out in a basic solution is known as saponification reaction.

Interpretation Introduction

(c)

Interpretation:

The products formed when cocaine is treated with an excess of concentrated aqueous HCl and heat is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

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Answer 5

Chapter 23, Problem 23.50AP

Interpretation Introduction

(a)

Interpretation:

The structure of cocaine which is expected to present in 1 M aqueous HCl solution is to be predicted.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Interpretation Introduction

(b)

Interpretation:

The products formed when cocaine is treated with an excess of aqueous NaOH and heat are to be predicted.

Concept introduction:

Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid. A hydrolysis reaction of ester carried out in a basic solution is known as saponification reaction.

Interpretation Introduction

(c)

Interpretation:

The products formed when cocaine is treated with an excess of concentrated aqueous HCl and heat is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Answer 6

Chapter 23, Problem 23.50AP

Interpretation Introduction

(a)

Interpretation:

The structure of cocaine which is expected to present in 1 M aqueous HCl solution is to be predicted.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Answer 7

Chapter 23, Problem 23.50AP

Interpretation Introduction

(a)

Interpretation:

The structure of cocaine which is expected to present in 1 M aqueous HCl solution is to be predicted.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The products formed when cocaine is treated with an excess of aqueous NaOH and heat are to be predicted.

Concept introduction:

Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid. A hydrolysis reaction of ester carried out in a basic solution is known as saponification reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The products formed when cocaine is treated with an excess of aqueous NaOH and heat are to be predicted.

Concept introduction:

Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid. A hydrolysis reaction of ester carried out in a basic solution is known as saponification reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The products formed when cocaine is treated with an excess of concentrated aqueous HCl and heat is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The products formed when cocaine is treated with an excess of concentrated aqueous HCl and heat is to be stated.

Concept introduction:

Amines are the organic compounds that are formed by replacement of hydrogen from ammonia. Alkaloids are a natural organic compound that contains nitrogen in them. Alkaloids are originated from plants. Alkaloid can act as a beneficial drug or can act as a poison. Cocaine is a tropane alkaloid.

Answer 12

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Answer 14

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Answer 15

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the structure of cocaine, which is expected to present in aqueous HCl solution.

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Chapter 23 Solutions