ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 22.9, Problem 12P
Interpretation Introduction

Interpretation:

The synthesis of the given compounds by using benzene as a starting material are to be stated.

Concept Introduction:

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Aryl diazonium salts undergo variety of specific substitution reactions by replacing N2 (a very good leaving group) by the incoming Z group to form corresponding products.

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Mechanisms of these reactions vary with the nature of Z, Here Z is an atom or group of atoms.

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Predict the reactants used in the formation of the following compounds using Acid-Catalyzed dehydration reaction
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.. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show ll relevant stereochemistry [3 ONLY]. A H Br 1. NaCN 2 NaOH, H₂O, heat 3. H3O+ B. CH₂COOH 19000 1. LiAlH4 THF, heat 2 H₂O* C. CH Br 1. NaCN, acetone 2 H3O+, heat D. Br 1. Mg. ether 3. H₂O+ 2 CO₂ E. CN 1. (CH) CHMgBr, ether 2 H₂O+
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