ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 22, Problem 37P

Write the structure of the product formed on reaction of acetanilide with each of thefollowing:

(a) Lithium aluminum hydride, followed by water

(b) Nitric acid and sulfuric acid

(c) Sulfur trioxide and sulfuric acid

(d) Bromine in acetic acid

(e) tert-Butyl chloride , aluminum chloride

(f ) Acetyl chloride, aluminum chloride

(g) 6 M hydrochloric acid, reflux

(h) Aqueous sodium hydroxide, reflux

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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