Chemistry: The Molecular Nature of Matter
7th Edition
ISBN: 9781118516461
Author: Neil D. Jespersen, Alison Hyslop
Publisher: WILEY
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Textbook Question
Chapter 22, Problem 84RQ
How are the two DNA strands in a double helix structurally related?
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Draw the structures of the tripeptides gly–ala–ser and ser–ala– gly. How many other tripeptides are possible using these three amino acids?
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O NAMING AND DRAWING ORGANIC MOLECULES
Interpreting condensed chemical structures
Use this condensed chemical structure to complete the table below.
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NH₂ - CH — C — OH
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CH3
The condensed chemical structure of alanine
Some facts about the alanine molecule:
number of carbon-carbon single (C - C) bonds:
number of carbon-hydrogen single (C-H) bonds:
number of oxygen-hydrogen single (O - H) bonds:
number of nitrogen-hydrogen single (N - H) bonds:
number of lone pairs:
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0
☐
1
D
503
Jess
As we’ve discussed, a peptide bond is made when amino group of one amino acid combines with the carboxylic acid group of another amino acid (releasing a water molecule in the process). The C-N bond formed in this process is called a peptide bond. Peptide bonds have a few properties that might be unexpected. a) One property is that the molecular geometries around the C and N atom in the peptide bond are generally planar with bond angles of approximately 120 degrees. Provide an explanation for why the peptide bond would have this property, using Lewis structures, VSEPR theory and/or valence bond theory as appropriate.
Chapter 22 Solutions
Chemistry: The Molecular Nature of Matter
Ch. 22 - Prob. 1PECh. 22 - Prob. 2PECh. 22 - Prob. 3PECh. 22 - Practice Exercise 22.4
Write the IUPAC names of...Ch. 22 - Oxidation of an alcohol gave the following...Ch. 22 - Prob. 6PECh. 22 - Prob. 7PECh. 22 - Prob. 8PECh. 22 - Prob. 9PECh. 22 - Prob. 10PE
Ch. 22 - Complete the following equation by drawing...Ch. 22 - Prob. 12PECh. 22 - Prob. 13PECh. 22 - Prob. 14PECh. 22 - Prob. 15PECh. 22 - Label the hydrophobic and hydrophilic portions of...Ch. 22 - Draw a ribose ring and a deoxyribose ring. What is...Ch. 22 - Practice Exercise 22.18
Which base pairs match in...Ch. 22 - Prob. 1RQCh. 22 - Prob. 2RQCh. 22 - Prob. 3RQCh. 22 - Prob. 4RQCh. 22 - Prob. 5RQCh. 22 - Prob. 6RQCh. 22 - Prob. 7RQCh. 22 - Which of the following compounds has the higher...Ch. 22 - In general terms, why do functional groups impart...Ch. 22 - Prob. 10RQCh. 22 - What is the difference between geometric isomers...Ch. 22 - Prob. 12RQCh. 22 - No number is needed to identify the location of...Ch. 22 - Prob. 14RQCh. 22 - Prob. 15RQCh. 22 - Prob. 16RQCh. 22 - 22.17 In general terms, why doesn't benzene...Ch. 22 - Prob. 18RQCh. 22 - 22.19 Explain why is more soluble in water than ....Ch. 22 - Prob. 20RQCh. 22 - Prob. 21RQCh. 22 - Why do aldehydes and ketones have boiling points...Ch. 22 - Acetic acid boils at 118C, higher even than...Ch. 22 - Methyl ethanoate has many more atoms than its...Ch. 22 - Prob. 25RQCh. 22 - 22.26 Write condensed structures of the following...Ch. 22 - 3-Butanol is not a proper name, but a structure...Ch. 22 - Prob. 28RQCh. 22 - Prob. 29RQCh. 22 - Prob. 30RQCh. 22 - Prob. 31RQCh. 22 - Prob. 32RQCh. 22 - Amines, RNH2, do not have boiling points as high...Ch. 22 - A monofunctional organic nitrogen compound...Ch. 22 - Prob. 35RQCh. 22 - Prob. 36RQCh. 22 - Prob. 37RQCh. 22 - Write the products that can be expected to form in...Ch. 22 - Prob. 39RQCh. 22 - Prob. 40RQCh. 22 - 22.41 What do we mean by the term polymer...Ch. 22 - Prob. 42RQCh. 22 - Prob. 43RQCh. 22 - Prob. 44RQCh. 22 - Prob. 45RQCh. 22 - Prob. 46RQCh. 22 - Prob. 47RQCh. 22 - Prob. 48RQCh. 22 - Prob. 49RQCh. 22 - Prob. 50RQCh. 22 - Prob. 51RQCh. 22 - Prob. 52RQCh. 22 - Prob. 53RQCh. 22 - Prob. 54RQCh. 22 - Prob. 55RQCh. 22 - Prob. 56RQCh. 22 - Prob. 57RQCh. 22 - Prob. 58RQCh. 22 - What are the three fundamental needs for...Ch. 22 - Prob. 60RQCh. 22 - Prob. 61RQCh. 22 - Prob. 62RQCh. 22 - Name the compounds that form when sucrose is...Ch. 22 - Prob. 64RQCh. 22 - Prob. 65RQCh. 22 - Prob. 66RQCh. 22 - Prob. 67RQCh. 22 - 22.68 What function is served by glycogen in the...Ch. 22 - How are lipids defined?Ch. 22 - Why are lipids more soluble than carbohydrates in...Ch. 22 - 22.71 Cholesterol is not an ester, yet it is...Ch. 22 - A product such as corn oil is advertised as...Ch. 22 - Is it likely that the following compound could be...Ch. 22 - Describe the specific ways in which the monomers...Ch. 22 - What is the peptide bond? How is it similar to the...Ch. 22 - Prob. 76RQCh. 22 - Prob. 77RQCh. 22 - Why is a distinction made between the terms...Ch. 22 - Prob. 79RQCh. 22 - What kind of substance makes up most enzymes?Ch. 22 - Prob. 81RQCh. 22 - Prob. 82RQCh. 22 - Prob. 83RQCh. 22 - 22.84 How are the two DNA strands in a double...Ch. 22 - In what ways do DNA and RNA differ structurally.Ch. 22 - 22.86 Which base pairs with
Ch. 22 - The process of transcription begins with which...Ch. 22 - The process of translation begins with which...Ch. 22 - Prob. 89RQCh. 22 - 22.90 Write full (expanded) structures for each of...Ch. 22 - Prob. 91RQCh. 22 - Prob. 92RQCh. 22 - Prob. 93RQCh. 22 - Prob. 94RQCh. 22 - Prob. 95RQCh. 22 - Prob. 96RQCh. 22 - Prob. 97RQCh. 22 - Prob. 98RQCh. 22 - Prob. 99RQCh. 22 - Prob. 100RQCh. 22 - Prob. 101RQCh. 22 - 22.102 Write the structures of the cis and tram...Ch. 22 - 22.103 Write the structures of the products that...Ch. 22 - Prob. 104RQCh. 22 - 22.105 Repeat Problem 22.103 using...Ch. 22 - Repeat Problem 22.104 using cyclohexene. The...Ch. 22 - Prob. 107RQCh. 22 - Predict the products of the reaction of benzene...Ch. 22 - Prob. 109RQCh. 22 - Prob. 110RQCh. 22 - Prob. 111RQCh. 22 - Prob. 112RQCh. 22 - Prob. 113RQCh. 22 - Write the structure of the product of the...Ch. 22 - Prob. 115RQCh. 22 - Prob. 116RQCh. 22 - Prob. 117RQCh. 22 - Prob. 118RQCh. 22 - Prob. 119RQCh. 22 - Prob. 120RQCh. 22 - Prob. 121RQCh. 22 - Write the structures of the products that form in...Ch. 22 - Prob. 123RQCh. 22 - Prob. 124RQCh. 22 - Prob. 125RQCh. 22 - Prob. 126RQCh. 22 - Prob. 127RQCh. 22 - Prob. 128RQCh. 22 - 22.129 Write the structure of a triacylglycerol...Ch. 22 - 22.130 Write the structures of the products of the...Ch. 22 - Write the structure of the triacylglycerol that...Ch. 22 - *22.132 If the compound in Problem 22.130 is...Ch. 22 - *22.133 What parts of glyccrophospholipid...Ch. 22 - *22.134 In general terms, describe the structure...Ch. 22 - Prob. 135RQCh. 22 - What is the structure of the tripeptide that could...Ch. 22 - 22.137 What are the structures of the two...Ch. 22 - Prob. 138RQCh. 22 - Prob. 139RQCh. 22 - Prob. 140RQCh. 22 - Prob. 141RQCh. 22 - 22.142 Suggest a reason why trimethylamine, , has...Ch. 22 - Prob. 143RQCh. 22 - How many tripeptides can be made from three...Ch. 22 - Prob. 145RQCh. 22 - Prob. 146RQCh. 22 - Estimate the number of kilojoules of heat that...Ch. 22 - Prob. 148RQCh. 22 - Prob. 149RQCh. 22 - The compound that causes your eyes to water when...Ch. 22 - Prob. 151RQCh. 22 - Prob. 152RQCh. 22 - Use resonance structures to explain why urea,...Ch. 22 - Prob. 154RQCh. 22 - Prob. 155RQ
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- what is the term used to describe organic reactions in which each atom of a diatomic molecule is transferred to one of the carbons in a double bond?arrow_forwardAdenine and guanine are the members of a class of molecules known as purines; they have two rings in their structure. Thymine and cytosine, on the other hand, are pyrimidines and have only one ring in their structure. Predict which have larger dispersion forces in aqueous solution.arrow_forwarda. Use bond energies (see Table 3-3) to estimate H for the reaction of two molecules of glycine to form a peptide linkage. b. Would you predict S to favor the formation of peptide linkages between two molecules of glycine? c. Would you predict the formation of proteins to be a spontaneous process?arrow_forward
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