Chemistry: The Molecular Nature of Matter

7th Edition

ISBN: 9781118516461

Author: Neil D. Jespersen, Alison Hyslop

Publisher: WILEY

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Textbook Question

Chapter 22, Problem 71RQ

Cholesterol is not an ester, yet it is defined as a lipid. Why?

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Chapter 22, Problem 70RQ

Chapter 22, Problem 72RQ

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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…

b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm

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Chapter 22 Solutions

Chemistry: The Molecular Nature of Matter

Ch. 22 - Prob. 1PE Ch. 22 - Prob. 2PE Ch. 22 - Prob. 3PE Ch. 22 - Practice Exercise 22.4 Write the IUPAC names of...Ch. 22 - Oxidation of an alcohol gave the following...Ch. 22 - Prob. 6PE Ch. 22 - Prob. 7PE Ch. 22 - Prob. 8PE Ch. 22 - Prob. 9PE Ch. 22 - Prob. 10PE

Ch. 22 - Complete the following equation by drawing...Ch. 22 - Prob. 12PE Ch. 22 - Prob. 13PE Ch. 22 - Prob. 14PE Ch. 22 - Prob. 15PE Ch. 22 - Label the hydrophobic and hydrophilic portions of...Ch. 22 - Draw a ribose ring and a deoxyribose ring. What is...Ch. 22 - Practice Exercise 22.18 Which base pairs match in...Ch. 22 - Prob. 1RQ Ch. 22 - Prob. 2RQ Ch. 22 - Prob. 3RQ Ch. 22 - Prob. 4RQ Ch. 22 - Prob. 5RQ Ch. 22 - Prob. 6RQ Ch. 22 - Prob. 7RQ Ch. 22 - Which of the following compounds has the higher...Ch. 22 - In general terms, why do functional groups impart...Ch. 22 - Prob. 10RQ Ch. 22 - What is the difference between geometric isomers...Ch. 22 - Prob. 12RQ Ch. 22 - No number is needed to identify the location of...Ch. 22 - Prob. 14RQ Ch. 22 - Prob. 15RQ Ch. 22 - Prob. 16RQ Ch. 22 - 22.17 In general terms, why doesn't benzene...Ch. 22 - Prob. 18RQ Ch. 22 - 22.19 Explain why is more soluble in water than ....Ch. 22 - Prob. 20RQ Ch. 22 - Prob. 21RQ Ch. 22 - Why do aldehydes and ketones have boiling points...Ch. 22 - Acetic acid boils at 118C, higher even than...Ch. 22 - Methyl ethanoate has many more atoms than its...Ch. 22 - Prob. 25RQ Ch. 22 - 22.26 Write condensed structures of the following...Ch. 22 - 3-Butanol is not a proper name, but a structure...Ch. 22 - Prob. 28RQ Ch. 22 - Prob. 29RQ Ch. 22 - Prob. 30RQ Ch. 22 - Prob. 31RQ Ch. 22 - Prob. 32RQ Ch. 22 - Amines, RNH2, do not have boiling points as high...Ch. 22 - A monofunctional organic nitrogen compound...Ch. 22 - Prob. 35RQ Ch. 22 - Prob. 36RQ Ch. 22 - Prob. 37RQ Ch. 22 - Write the products that can be expected to form in...Ch. 22 - Prob. 39RQ Ch. 22 - Prob. 40RQ Ch. 22 - 22.41 What do we mean by the term polymer...Ch. 22 - Prob. 42RQ Ch. 22 - Prob. 43RQ Ch. 22 - Prob. 44RQ Ch. 22 - Prob. 45RQ Ch. 22 - Prob. 46RQ Ch. 22 - Prob. 47RQ Ch. 22 - Prob. 48RQ Ch. 22 - Prob. 49RQ Ch. 22 - Prob. 50RQ Ch. 22 - Prob. 51RQ Ch. 22 - Prob. 52RQ Ch. 22 - Prob. 53RQ Ch. 22 - Prob. 54RQ Ch. 22 - Prob. 55RQ Ch. 22 - Prob. 56RQ Ch. 22 - Prob. 57RQ Ch. 22 - Prob. 58RQ Ch. 22 - What are the three fundamental needs for...Ch. 22 - Prob. 60RQ Ch. 22 - Prob. 61RQ Ch. 22 - Prob. 62RQ Ch. 22 - Name the compounds that form when sucrose is...Ch. 22 - Prob. 64RQ Ch. 22 - Prob. 65RQ Ch. 22 - Prob. 66RQ Ch. 22 - Prob. 67RQ Ch. 22 - 22.68 What function is served by glycogen in the...Ch. 22 - How are lipids defined?Ch. 22 - Why are lipids more soluble than carbohydrates in...Ch. 22 - 22.71 Cholesterol is not an ester, yet it is...Ch. 22 - A product such as corn oil is advertised as...Ch. 22 - Is it likely that the following compound could be...Ch. 22 - Describe the specific ways in which the monomers...Ch. 22 - What is the peptide bond? How is it similar to the...Ch. 22 - Prob. 76RQ Ch. 22 - Prob. 77RQ Ch. 22 - Why is a distinction made between the terms...Ch. 22 - Prob. 79RQ Ch. 22 - What kind of substance makes up most enzymes?Ch. 22 - Prob. 81RQ Ch. 22 - Prob. 82RQ Ch. 22 - Prob. 83RQ Ch. 22 - 22.84 How are the two DNA strands in a double...Ch. 22 - In what ways do DNA and RNA differ structurally.Ch. 22 - 22.86 Which base pairs with Ch. 22 - The process of transcription begins with which...Ch. 22 - The process of translation begins with which...Ch. 22 - Prob. 89RQ Ch. 22 - 22.90 Write full (expanded) structures for each of...Ch. 22 - Prob. 91RQ Ch. 22 - Prob. 92RQ Ch. 22 - Prob. 93RQ Ch. 22 - Prob. 94RQ Ch. 22 - Prob. 95RQ Ch. 22 - Prob. 96RQ Ch. 22 - Prob. 97RQ Ch. 22 - Prob. 98RQ Ch. 22 - Prob. 99RQ Ch. 22 - Prob. 100RQ Ch. 22 - Prob. 101RQ Ch. 22 - 22.102 Write the structures of the cis and tram...Ch. 22 - 22.103 Write the structures of the products that...Ch. 22 - Prob. 104RQ Ch. 22 - 22.105 Repeat Problem 22.103 using...Ch. 22 - Repeat Problem 22.104 using cyclohexene. The...Ch. 22 - Prob. 107RQ Ch. 22 - Predict the products of the reaction of benzene...Ch. 22 - Prob. 109RQ Ch. 22 - Prob. 110RQ Ch. 22 - Prob. 111RQ Ch. 22 - Prob. 112RQ Ch. 22 - Prob. 113RQ Ch. 22 - Write the structure of the product of the...Ch. 22 - Prob. 115RQ Ch. 22 - Prob. 116RQ Ch. 22 - Prob. 117RQ Ch. 22 - Prob. 118RQ Ch. 22 - Prob. 119RQ Ch. 22 - Prob. 120RQ Ch. 22 - Prob. 121RQ Ch. 22 - Write the structures of the products that form in...Ch. 22 - Prob. 123RQ Ch. 22 - Prob. 124RQ Ch. 22 - Prob. 125RQ Ch. 22 - Prob. 126RQ Ch. 22 - Prob. 127RQ Ch. 22 - Prob. 128RQ Ch. 22 - 22.129 Write the structure of a triacylglycerol...Ch. 22 - 22.130 Write the structures of the products of the...Ch. 22 - Write the structure of the triacylglycerol that...Ch. 22 - *22.132 If the compound in Problem 22.130 is...Ch. 22 - *22.133 What parts of glyccrophospholipid...Ch. 22 - *22.134 In general terms, describe the structure...Ch. 22 - Prob. 135RQ Ch. 22 - What is the structure of the tripeptide that could...Ch. 22 - 22.137 What are the structures of the two...Ch. 22 - Prob. 138RQ Ch. 22 - Prob. 139RQ Ch. 22 - Prob. 140RQ Ch. 22 - Prob. 141RQ Ch. 22 - 22.142 Suggest a reason why trimethylamine, , has...Ch. 22 - Prob. 143RQ Ch. 22 - How many tripeptides can be made from three...Ch. 22 - Prob. 145RQ Ch. 22 - Prob. 146RQ Ch. 22 - Estimate the number of kilojoules of heat that...Ch. 22 - Prob. 148RQ Ch. 22 - Prob. 149RQ Ch. 22 - The compound that causes your eyes to water when...Ch. 22 - Prob. 151RQ Ch. 22 - Prob. 152RQ Ch. 22 - Use resonance structures to explain why urea,...Ch. 22 - Prob. 154RQ Ch. 22 - Prob. 155RQ

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