Chapter 22, Problem 66PP

(a)

Interpretation Introduction

Interpretation: The products of the reactions in which diazonium salt is treated with the given reagents have to be drawn.

Concept Introduction:

A compound containing an amino group is treated with sodium nitrite and HCl leading to the formation of diazonium salt.

Sandmeyer reactions use copper salts as the reagents.  Here, aryldiazonium salt is converted into aryl halides or aryl cyanides by using copper halides or copper cyanides.

Schiemann reaction is the reaction in which diazonium salt is converted into fluoro group using fluoroboric acid (HBF₄).

To find: Get the product of the reaction in which diazonium salt is treated with the given reagent (a)

Put the reaction of m-bromoaniline with NaNO₂ and HCl

(b)

Interpretation Introduction

Interpretation: The products of the reactions in which diazonium salt is treated with the given reagents have to be drawn.

Concept Introduction:

A compound containing an amino group is treated with sodium nitrite and HCl leading to the formation of diazonium salt.

Sandmeyer reactions use copper salts as the reagents.  Here, aryldiazonium salt is converted into aryl halides or aryl cyanides by using copper halides or copper cyanides.

Schiemann reaction is the reaction in which diazonium salt is converted into fluoro group using fluoroboric acid (HBF₄).

To find: Get the product of the reaction in which diazonium salt is treated with the given reagent (b)

Put the reaction of m-bromoaniline with NaNO₂ and HCl

(c)

Interpretation Introduction

Interpretation: The products of the reactions in which diazonium salt is treated with the given reagents have to be drawn.

Concept Introduction:

A compound containing an amino group is treated with sodium nitrite and HCl leading to the formation of diazonium salt.

Sandmeyer reactions use copper salts as the reagents.  Here, aryldiazonium salt is converted into aryl halides or aryl cyanides by using copper halides or copper cyanides.

Schiemann reaction is the reaction in which diazonium salt is converted into fluoro group using fluoroboric acid (HBF₄).

To find: Get the product of the reaction in which diazonium salt is treated with the given reagent

Put the reaction of m-bromoaniline with NaNO₂ and HCl

(d)

Interpretation Introduction

Interpretation: The products of the reactions in which diazonium salt is treated with the given reagents have to be drawn.

Concept Introduction:

A compound containing an amino group is treated with sodium nitrite and HCl leading to the formation of diazonium salt.

Sandmeyer reactions use copper salts as the reagents.  Here, aryldiazonium salt is converted into aryl halides or aryl cyanides by using copper halides or copper cyanides.

Schiemann reaction is the reaction in which diazonium salt is converted into fluoro group using fluoroboric acid (HBF₄).

To find: Get the product of the reaction in which diazonium salt is treated with the given reagent

Put the reaction of m-bromoaniline with NaNO₂ and HCl

(e)

Interpretation Introduction

Interpretation: The products of the reactions in which diazonium salt is treated with the given reagents have to be drawn.

Concept Introduction:

A compound containing an amino group is treated with sodium nitrite and HCl leading to the formation of diazonium salt.

Sandmeyer reactions use copper salts as the reagents.  Here, aryldiazonium salt is converted into aryl halides or aryl cyanides by using copper halides or copper cyanides.

Schiemann reaction is the reaction in which diazonium salt is converted into fluoro group using fluoroboric acid (HBF₄).

To find: Get the product of the reaction in which diazonium salt is treated with the given reagent (e)

Put the reaction of m-bromoaniline with NaNO₂ and HCl