ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS
ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS
4th Edition
ISBN: 9781119830474
Author: Klein
Publisher: WILEY
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Chapter 22, Problem 87IP
Interpretation Introduction

Interpretation: The possible structure for the compound C6H15N that exhibits two types of signals in its proton NMR spectrum and two signals in 13C NMR spectrum has to be drawn.

Concept introduction:

The arrangement of atoms that are bonded together determines its constitution and molecular formula of that particular compound.  This concept is referred as structural isomers or in more modern term constitutional isomers.  Each atom has a typical valency or valence which is defined as the ability of an atom to form a chemical bond with other atoms.  For example, carbon has four valence or tetravalent that means carbon has the capacity to form four bonds with other elements or other atoms.  Nitrogen atoms are trivalent whereas hydrogen atoms are monovalent in nature.

In proton NMR, the signals are based on the arrangement of hydrogen atoms that are connected to carbon atoms.  In 13C NMR, the signals are based on the arrangement of carbon atoms.

To find: Draw the possible structure for the compound C6H15N that exhibits two types of signals in its proton NMR spectrum and two signals in 13C NMR spectrum

Find the valency for carbon (C), hydrogen (H) and nitrogen (N) in C6H15N

ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS, Chapter 22, Problem 87IP

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The Concept of Aromaticity 21.15 State the number of 2p orbital electrons in each molecule or ion. (a) (b) (e) (f) (c) (d) (h) (i) DA (k) 21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the Hückel criteria? Which, if planar, would be antiaromatic? 21.17 Which of the following structures are considered aromatic according to the Hückel criteria? ---0-0 (a) (b) (c) (d) (e) (h) H -H .8.0- 21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a heteroatom?
1. Show the steps necessary to make 2-methyl-4-nonene using a Wittig reaction. Start with triphenylphosphine and an alkyl halide. After that you may use any other organic or inorganic reagents. 2. Write in the product of this reaction: CH3 CH₂ (C6H5)₂CuLi H₂O+
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Chapter 22 Solutions

ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS

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