ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS
ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS
4th Edition
ISBN: 9781119830474
Author: Klein
Publisher: WILEY
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Chapter 22.8, Problem 20CC
Interpretation Introduction

Interpretation: A plausible method for converting aniline into para-nitroaniline has to be found.

Concept Introduction:

Acetylation of an aromatic ring leads to the introduction of acetyl group in the functional group attached to the ring such as in amino group.  This is achieved by using acetyl chloride.  A mixture of nitric acid and sulfuric acid is called a nitrating mixture.  It leads the aromatic ring for the introduction of nitro group.  Deacetylation means the removal of acetyl group which is done by aqueous acidic or basic conditions.

To find: Convert aniline into para-nitroaniline by a plausible method

Do acetylation in aniline using acetyl chloride

ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS, Chapter 22.8, Problem 20CC

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1. Show the steps necessary to make 2-methyl-4-nonene using a Wittig reaction. Start with triphenylphosphine and an alkyl halide. After that you may use any other organic or inorganic reagents. 2. Write in the product of this reaction: CH3 CH₂ (C6H5)₂CuLi H₂O+
3. Name this compound properly, including stereochemistry. H₂C H3C CH3 OH 4. Show the step(s) necessary to transform the compound on the left into the acid on the right. Bri CH2 5. Write in the product of this LiAlH4 Br H₂C OH
What are the major products of the following reaction? Please provide a detailed explanation and a drawing to show how the reaction proceeds.

Chapter 22 Solutions

ORGANIC CHEMISTRY(EBOOK)-W/WILEYPLUS

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