The basic character of nitrogen atom by comparing with oxygen atom has to be studied by taking an example of an amide and its protonation behavior towards the strong acidic condition. Concept Introduction : Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa. To find: Compare the basic character of nitrogen atom with oxygen atom in amide and its protonation behavior towards the strong acidic condition Find the delocalization behavior of a cation on oxygen atom in an amide

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 53PP

Interpretation Introduction

Interpretation: The basic character of nitrogen atom by comparing with oxygen atom has to be studied by taking an example of an amide and its protonation behavior towards the strong acidic condition.

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: Compare the basic character of nitrogen atom with oxygen atom in amide and its protonation behavior towards the strong acidic condition

Find the delocalization behavior of a cation on oxygen atom in an amide

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First image: I have to explain why the molecule C is never formed in these conditions Second image: I have to propose a synthesis for the lactone A

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Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 53PP

Interpretation Introduction

Interpretation: The basic character of nitrogen atom by comparing with oxygen atom has to be studied by taking an example of an amide and its protonation behavior towards the strong acidic condition.

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: Compare the basic character of nitrogen atom with oxygen atom in amide and its protonation behavior towards the strong acidic condition

Find the delocalization behavior of a cation on oxygen atom in an amide

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 53PP

Interpretation Introduction

Interpretation: The basic character of nitrogen atom by comparing with oxygen atom has to be studied by taking an example of an amide and its protonation behavior towards the strong acidic condition.

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: Compare the basic character of nitrogen atom with oxygen atom in amide and its protonation behavior towards the strong acidic condition

Find the delocalization behavior of a cation on oxygen atom in an amide

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 53PP

Interpretation Introduction