(a) Interpretation: The structures of three monobromo derivatives obtained from reaction of 2 − methylcyclohexanone with Br 2 in presence of HBr are to be predicted. Concept introduction: In organic chemistry , the carbonyl compound is a class of functional group which contains a C = O group. They are of two types. aldehyde − CHO and ketone RC = OR . They are the oxidized product of alcohol. Halogenation reaction of carbonyl compounds takes place in the presence of Cl 2 , Br 2 , SO 2 Cl 2 and so on. It may result in the formation of enol and enolate ion in case of saturated compounds.

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Chapter 22, Problem 22.66AP

Interpretation Introduction

(a)

Interpretation:

The structures of three monobromo derivatives obtained from reaction of 2−methylcyclohexanone with Br2 in presence of HBr are to be predicted.

Concept introduction:

In organic chemistry, the carbonyl compound is a class of functional group which contains a C=O group. They are of two types. aldehyde −CHO and ketone RC=OR. They are the oxidized product of alcohol. Halogenation reaction of carbonyl compounds takes place in the presence of Cl2, Br2, SO2Cl2 and so on. It may result in the formation of enol and enolate ion in case of saturated compounds.

Interpretation Introduction

(b)

Interpretation:

The isomer in part (a) which is obtained from the most stable enol is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It is possible in either way acid or base-catalyzed.

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Answer 2

Question

Chapter 22, Problem 22.66AP

Interpretation Introduction

(a)

Interpretation:

The structures of three monobromo derivatives obtained from reaction of 2−methylcyclohexanone with Br2 in presence of HBr are to be predicted.

Concept introduction:

In organic chemistry, the carbonyl compound is a class of functional group which contains a C=O group. They are of two types. aldehyde −CHO and ketone RC=OR. They are the oxidized product of alcohol. Halogenation reaction of carbonyl compounds takes place in the presence of Cl2, Br2, SO2Cl2 and so on. It may result in the formation of enol and enolate ion in case of saturated compounds.

Interpretation Introduction

(b)

Interpretation:

The isomer in part (a) which is obtained from the most stable enol is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It is possible in either way acid or base-catalyzed.

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Answer 3

Question

Chapter 22, Problem 22.66AP

Interpretation Introduction

(a)

Interpretation:

The structures of three monobromo derivatives obtained from reaction of 2−methylcyclohexanone with Br2 in presence of HBr are to be predicted.

Concept introduction:

In organic chemistry, the carbonyl compound is a class of functional group which contains a C=O group. They are of two types. aldehyde −CHO and ketone RC=OR. They are the oxidized product of alcohol. Halogenation reaction of carbonyl compounds takes place in the presence of Cl2, Br2, SO2Cl2 and so on. It may result in the formation of enol and enolate ion in case of saturated compounds.

Interpretation Introduction

(b)

Interpretation:

The isomer in part (a) which is obtained from the most stable enol is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It is possible in either way acid or base-catalyzed.

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Answer 4

Question

Chapter 22, Problem 22.66AP

Interpretation Introduction

(a)

Interpretation:

The structures of three monobromo derivatives obtained from reaction of 2−methylcyclohexanone with Br2 in presence of HBr are to be predicted.

Concept introduction:

In organic chemistry, the carbonyl compound is a class of functional group which contains a C=O group. They are of two types. aldehyde −CHO and ketone RC=OR. They are the oxidized product of alcohol. Halogenation reaction of carbonyl compounds takes place in the presence of Cl2, Br2, SO2Cl2 and so on. It may result in the formation of enol and enolate ion in case of saturated compounds.

Interpretation Introduction

(b)

Interpretation:

The isomer in part (a) which is obtained from the most stable enol is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It is possible in either way acid or base-catalyzed.

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Answer 5

Chapter 22, Problem 22.66AP

Interpretation Introduction

(a)

Interpretation:

The structures of three monobromo derivatives obtained from reaction of 2−methylcyclohexanone with Br2 in presence of HBr are to be predicted.

Concept introduction:

In organic chemistry, the carbonyl compound is a class of functional group which contains a C=O group. They are of two types. aldehyde −CHO and ketone RC=OR. They are the oxidized product of alcohol. Halogenation reaction of carbonyl compounds takes place in the presence of Cl2, Br2, SO2Cl2 and so on. It may result in the formation of enol and enolate ion in case of saturated compounds.

Interpretation Introduction

(b)

Interpretation:

The isomer in part (a) which is obtained from the most stable enol is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It is possible in either way acid or base-catalyzed.

Answer 6

Chapter 22, Problem 22.66AP

Interpretation Introduction

(a)

Interpretation:

The structures of three monobromo derivatives obtained from reaction of 2−methylcyclohexanone with Br2 in presence of HBr are to be predicted.

Concept introduction:

In organic chemistry, the carbonyl compound is a class of functional group which contains a C=O group. They are of two types. aldehyde −CHO and ketone RC=OR. They are the oxidized product of alcohol. Halogenation reaction of carbonyl compounds takes place in the presence of Cl2, Br2, SO2Cl2 and so on. It may result in the formation of enol and enolate ion in case of saturated compounds.

Answer 7

Chapter 22, Problem 22.66AP

Interpretation Introduction

(a)

Interpretation:

The structures of three monobromo derivatives obtained from reaction of 2−methylcyclohexanone with Br2 in presence of HBr are to be predicted.

Concept introduction:

In organic chemistry, the carbonyl compound is a class of functional group which contains a C=O group. They are of two types. aldehyde −CHO and ketone RC=OR. They are the oxidized product of alcohol. Halogenation reaction of carbonyl compounds takes place in the presence of Cl2, Br2, SO2Cl2 and so on. It may result in the formation of enol and enolate ion in case of saturated compounds.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The isomer in part (a) which is obtained from the most stable enol is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It is possible in either way acid or base-catalyzed.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The isomer in part (a) which is obtained from the most stable enol is to be stated.

Concept introduction:

Tautomers are isomers which differ only in the position of the protons and electrons of the double bond of the electronegative atom in the compound. There is no change in the carbon skeleton of the compound. This phenomenon which involves simple proton transfer in an intramolecular fashion is known as tautomerism. The very common example of tautomerism is Keto-enol tautomerism. It is possible in either way acid or base-catalyzed.

Answer 10

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that the structures of three monobromo derivatives obtained from reaction of 2-methylcyclohexanone with

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