(a) Interpretation: The product formed on reaction of 1 − bromo − 2 − butanone with pyridine is to be stated. Concept introduction: The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile. The S N 2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously. The S N 1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Answer 1

Question

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Use solubility rules to provide balance molecular equation, total, and net ionic equation

Br HO ? HO ✓ OH

Use the literature Ka value of the acetic acid, and the data below to answer these questions. Note: You will not use the experimental titration graphs to answer the questions that follow. Group #1: Buffer pH = 4.35 Group #2: Buffer pH = 4.70 Group #3: Buffer pH = 5.00 Group #4: Buffer pH = 5.30 Use the Henderson-Hasselbalch equation, the buffer pH provided and the literature pKa value of acetic acid to perform the following: a) calculate the ratios of [acetate]/[acetic acid] for each of the 4 groups buffer solutions above. b) using the calculated ratios, which group solution will provide the best optimal buffer (Hint: what [acetate]/[acetic acid] ratio value is expected for an optimal buffer?) c) explain your choice

Answer 2

Question

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Answer 3

Question

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Answer 4

Question

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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Answer 5

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 6

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 7

Chapter 22, Problem 22.17P

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1−bromo−2−butanone with pyridine is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which nucleophile attacks the electrophilic centre and eliminates another group. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of α−bromoacetophenone with sodium acetate is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Answer 10

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that the product formed on reaction of 1-bromo-2- butanone with pyridine is to be stated.

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Chapter 22 Solutions