(a) Interpretation: The structure of an optically active compound C 6 H 12 O that racemizes in base is to be stated. Concept introduction: The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α -carbon . The optically active aldehyde racemize having chiral α -carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Question

Want to see the full answer?

Answer 1

Question

Chapter 22, Problem 22.58AP

Interpretation Introduction

(a)

Interpretation:

The structure of an optically active compound C6H12O that racemizes in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(b)

Interpretation:

The structure of an achiral compound C6H12O that does not give a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(c)

Interpretation:

The structure of an optically active compound C6H12O that neither racemizes in base nor gives a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(d)

Interpretation:

The structure of an optically active compound C6H12O that gives a positive Tollens test and does not racemize in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically: 1:1 (one mole of EDTA per mole of metal ion) 2:1 (two moles of EDTA per mole of metal ion) 1:2 (one mole of EDTA per two moles of metal ion) None of the above

Please help me solve this reaction.

Indicate the products obtained by mixing 2,2-dimethylpropanal with acetaldehyde and sodium ethoxide in ethanol.

Answer 2

Question

Chapter 22, Problem 22.58AP

Interpretation Introduction

(a)

Interpretation:

The structure of an optically active compound C6H12O that racemizes in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(b)

Interpretation:

The structure of an achiral compound C6H12O that does not give a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(c)

Interpretation:

The structure of an optically active compound C6H12O that neither racemizes in base nor gives a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(d)

Interpretation:

The structure of an optically active compound C6H12O that gives a positive Tollens test and does not racemize in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 22, Problem 22.58AP

Interpretation Introduction

(a)

Interpretation:

The structure of an optically active compound C6H12O that racemizes in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(b)

Interpretation:

The structure of an achiral compound C6H12O that does not give a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(c)

Interpretation:

The structure of an optically active compound C6H12O that neither racemizes in base nor gives a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(d)

Interpretation:

The structure of an optically active compound C6H12O that gives a positive Tollens test and does not racemize in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 22, Problem 22.58AP

Interpretation Introduction

(a)

Interpretation:

The structure of an optically active compound C6H12O that racemizes in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(b)

Interpretation:

The structure of an achiral compound C6H12O that does not give a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(c)

Interpretation:

The structure of an optically active compound C6H12O that neither racemizes in base nor gives a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(d)

Interpretation:

The structure of an optically active compound C6H12O that gives a positive Tollens test and does not racemize in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 22, Problem 22.58AP

Interpretation Introduction

(a)

Interpretation:

The structure of an optically active compound C6H12O that racemizes in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(b)

Interpretation:

The structure of an achiral compound C6H12O that does not give a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(c)

Interpretation:

The structure of an optically active compound C6H12O that neither racemizes in base nor gives a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Interpretation Introduction

(d)

Interpretation:

The structure of an optically active compound C6H12O that gives a positive Tollens test and does not racemize in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 6

Chapter 22, Problem 22.58AP

Interpretation Introduction

(a)

Interpretation:

The structure of an optically active compound C6H12O that racemizes in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 7

Chapter 22, Problem 22.58AP

Interpretation Introduction

(a)

Interpretation:

The structure of an optically active compound C6H12O that racemizes in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of an achiral compound C6H12O that does not give a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of an achiral compound C6H12O that does not give a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of an optically active compound C6H12O that neither racemizes in base nor gives a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of an optically active compound C6H12O that neither racemizes in base nor gives a positive Tollens test is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure of an optically active compound C6H12O that gives a positive Tollens test and does not racemize in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure of an optically active compound C6H12O that gives a positive Tollens test and does not racemize in base is to be stated.

Concept introduction:

The carbonyl compound racemizes in the presence of base if their optical activity depends on the chirality of the α-carbon. The optically active aldehyde racemize having chiral α-carbon because hydrogen can attach from either of two faces on the enolate ion formed.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains that an optically active compound racemizes in base if its optical activity depends on the chirality of the alpha-carbon.

Concept explainers

Want to see the full answer?

Chapter 22 Solutions