(a) Interpretation: The product formed on Aldol condensation in the given reaction is to be stated. Concept introduction: In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β -hydroxyaldehyde or β -hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 1

Question

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. NaN₃

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Answer 2

Question

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 3

Question

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 4

Question

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 5

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 6

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 7

Chapter 22, Problem 22.21P

Interpretation Introduction

(a)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed on Aldol condensation in the given reaction is to be stated

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The product formed on aldol condensation in the given reaction is to be stated.

Concept introduction:

In Aldol condensation reaction, the base abstracts an acidic proton from the α carbon atom to form enolate. This enolate or enol reacts with carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

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