Concept explainers
(a)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one
Answer to Problem 22.48P
No product is formed by the treatment of ethyl butanoate with
Explanation of Solution
Esters do not undergo reaction with
Figure 1
No product is formed by the treatment of ethyl butanoate with
(b)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.48P
The product formed by the treatment of ethyl butanoate
Explanation of Solution
Esters undergo hydrolysis under acidic and basic medium. In the given reaction, ester undergoes hydrolysis under acidic medium. One mole of
Figure 2
The product formed by the treatment of ethyl butanoate
(c)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.48P
The product formed by the treatment of ethyl butanoate
Explanation of Solution
Esters undergo hydrolysis under acidic and basic medium. In the given reaction, ester undergoes hydrolysis under basic medium. One mole of carboxylate ion and one mole of alcohol are produced from the hydrolysis of ethyl butanoate as shown in Figure 3.
Figure 3
The product formed by the treatment of ethyl butanoate
(d)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.48P
The product formed by the treatment of ethyl butanoate
Explanation of Solution
The reaction of ester with ammonia leads to the formation of amide and alcohol. The nitrogen atom of ammonia contains lone pair of electrons. The nitrogen atom acts as a nucleophile and attacks on the electron deficient carbonyl carbon atom of ester. The products formed by the reaction of ethyl butanoate with
Figure 4
The product formed by the treatment of ethyl butanoate
(e)
Interpretation:
The product formed by the treatment of ethyl butanoate
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilic acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.48P
The product formed by the treatment of ethyl butanoate
Explanation of Solution
The reaction of ester with primary
Figure 5
The product formed by the treatment of ethyl butanoate
Want to see more full solutions like this?
Chapter 22 Solutions
Organic Chemistry
- (12) Which one of the following statements about fluo- rometry is FALSE? a) Fluorescence is better detected at 90 from the exci- tation direction. b) Fluorescence is typically shifted to longer wave- length from the excitation wavelength. c) For most fluorescent compounds, radiation is pro- duced by a transitionarrow_forwardDon't used Ai solutionarrow_forwardDon't used Ai solutionarrow_forward
- Don't used Ai solutionarrow_forwardIndicate the correct option.a) Graphite conducts electricity, being an isotropic materialb) Graphite is not a conductor of electricityc) Both are falsearrow_forward(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):arrow_forward
- 1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):arrow_forward(c) SOCI Best Lewis Structure 2 e group arrangement: shape/molecular geometry:_ (d) PCls Best Lewis Structure polarity: e group geometry:_ shape/molecular geometry:_ (e) Ba(BrO2): Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):arrow_forwardDon't used Ai solutionarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY