Concept explainers
Videos
Give thestructure corresponding to each name.
a. propanoic anhydride g.
b.
c. cyclohexylpropanoate i. benzoic propanoic anhydride
d. cyclohexanecarboxamide j.
e. isopropyl formate k. octylbutanoate
f. N-cyclopentylpentanamide l. N, N-dibenzylformamide
(a)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains anhydride (name ends with -anhydride) as the functional group. This anhydride compound is derived from propionic acid.
Thus, the structure corresponding to the given name is,
Figure 1
The structure corresponding to the given name is drawn in Figure 1.
(b)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains acid chloride (name ends with -yl chloride) as the functional group, and butane as the longest carbon chain with one chloro substitution at
Thus, the structure corresponding to the given name is,
Figure 2
The structure corresponding to the given name is drawn in Figure 2.
(c)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is
Explanation of Solution
The given name indicates that compound contains ester (name ends with –ate) as the functional group, and propane as the longest carbon chain with one cyclohexyl substitution as
Thus, the structure corresponding to the given name is,
Figure 3
The structure corresponding to the given name is drawn in Figure 3.
(d)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains amide (name ends with -amide) as the functional group. This amide group is derived from cyclohexylcarboxylic acid, and bonded to cyclohexane ring.
Thus, the structure corresponding to given name is,
Figure 4
The structure corresponding to the given name is drawn in Figure 4.
(e)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is
Explanation of Solution
The given name indicates that compound contains ester (name ends with -ate) as the functional group, and an formate group is bonded to a isopropylgroup
Thus, the structure corresponding to the given name is,
Figure 5
The structure corresponding to the given name is drawn in Figure 5.
(f)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains amide (name ends with -amide) as the functional group. This amide group is derived from pentanoic acid, and
Thus, the structure corresponding to given name is,
Figure 6
The structure corresponding to the given name is drawn in Figure 6.
(g)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains cyano (name ends with -nitrile) as the functional group, and heptane as the longest carbon chain with one methyl substitution at
Thus, the structure corresponding to given name is,
Figure 7
The structure corresponding to the given name is drawn in Figure 7.
(h)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains ester (name ends with -ate) as the functional group, and an acetate group is bonded to a vinyl group
Thus, the structure corresponding to the given name is,
Figure 8
The structure corresponding to the given name is drawn in Figure 8.
(i)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains anhydride (name ends with -anhydride) as the functional group. This anhydride compound is derived from benzoic acid and propanoic acid.
Thus, the structure corresponding to the given name is,
Figure 9
The structure corresponding to the given name is drawn in Figure 9.
(j)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains acid chloride (name ends with -yl chloride) as the functional group, and hexane as the longest carbon chain with one methyl substitution at
Thus, the structure corresponding to the given name is,
Figure 10
The structure corresponding to the given name is drawn in Figure 10.
(k)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains ester (name ends with –ate) as the functional group, and butane as the longest carbon chain with one octyl substitution as
Thus, the structure corresponding to the given name is,
Figure 11
The structure corresponding to the given name is drawn in Figure 11.
(l)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains amide (name ends with -amide) as the functional group. This amide group is derived from formic acid, and bonded to two benzyl groups.
Thus, the structure corresponding to the given name is,
Figure 12
The structure corresponding to the given name is drawn in Figure 12.
Want to see more full solutions like this?
Chapter 22 Solutions
Organic Chemistry
- true or false Using the following equilibrium, if heat is added the equilibrium will shift toward the reactants. N2(g) + 3H2(g) ⇔ 2NH3(g) + heatarrow_forwardTrue or False Using the following equilibrium, if heat is added the equilibrium will shift toward the products. N2O4(g) + heat ⇔ 2NO2(g)arrow_forwardtrue or false Using the following equilibrium, if solid carbon is added the equilibrium will shift toward the products. C(s) + CO2(g) ⇔ 2CO(g)arrow_forward
- Provide the complete mechanism for the reaction below. You must include appropriate arrows,intermediates, and formal charges. Please also provide a reason to explain why the 1,4-adduct is preferred over the 1,3-adduct.arrow_forwardWhich of the following pairs are resonance structures of one another? I. III. || III IV + II. :0: n P !༠ IV. EN: Narrow_forwardPredict the major organic product(s) and byproducts (either organic or inorganic) for thefollowing reactions.arrow_forward
- A 8.25 g sample of aluminum at 55°C released 2500 J of heat. The specific heat of aluminum is 0.900 J/g°C. The density of aluminum is 2.70 g/mL. Calculate the final temperature of the aluminum sample in °C.arrow_forwardPredict the major organic product(s) and byproducts (either organic or inorganic) for thefollowing reactions.arrow_forwardPredict the major organic product(s) and byproducts (either organic or inorganic) for thefollowing reaction.arrow_forward
- please helparrow_forwardExperiment 1 Data Table 1: Conservation of Mass - Initial Mass Data Table 1 Data Table 2 Data Table 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Reaction Mass of test tube and 5.0% HC₂H₂O2 (g) # (A) (B) Mass of NaHCO, (g) Mass of balloon and NaHCO, (g) (C) 0.10 1 0829 14.38g 0.20 2 0.929 14.29g 0.35 1.00g 3 14.25g 0.50 1.14g 14.29 Experiment 1 Data Table 2: Moles of HC2H3O2 Reaction Volume of Mass of Moles of HC₂H₂O₂ 5.0% Vinegar (g) (ML) 5.0 0.25 0042 mol 2 5.0 0.25 0042 mol 3 5.0 0.25 0042 mol 5.0 0.25 0042 mol Experiment 1 Data Table 3: Moles of NaHCO3 Reaction Mass of NaHCO (g) 10g 20g 35g 50g Experiment 1 Data Table 4: Theoretical Yield of CO₂ Reaction # 1 2 3 Experiment 1 Total mass before reaction (g) (D=A+C) 15.29 15.21g 15.25g 15.349 Exercise 1 Data Table 1 Data Table 2 Data Table 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Exercise 1- Data Table 1 Data Table 2 DataTable 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Exercise 1- Moles of NaHCO 0012 mol 0025 mol 0044 mol 0062 mol…arrow_forwardThe chemical reaction you investigated is a two-step reaction. What type of reaction occurs in each step? How did you determine your answer?arrow_forward
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY