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Give thestructure corresponding to each name.
a. propanoic anhydride g.
b.
c. cyclohexylpropanoate i. benzoic propanoic anhydride
d. cyclohexanecarboxamide j.
e. isopropyl formate k. octylbutanoate
f. N-cyclopentylpentanamide l. N, N-dibenzylformamide
(a)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains anhydride (name ends with -anhydride) as the functional group. This anhydride compound is derived from propionic acid.
Thus, the structure corresponding to the given name is,
Figure 1
The structure corresponding to the given name is drawn in Figure 1.
(b)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains acid chloride (name ends with -yl chloride) as the functional group, and butane as the longest carbon chain with one chloro substitution at
Thus, the structure corresponding to the given name is,
Figure 2
The structure corresponding to the given name is drawn in Figure 2.
(c)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is
Explanation of Solution
The given name indicates that compound contains ester (name ends with –ate) as the functional group, and propane as the longest carbon chain with one cyclohexyl substitution as
Thus, the structure corresponding to the given name is,
Figure 3
The structure corresponding to the given name is drawn in Figure 3.
(d)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains amide (name ends with -amide) as the functional group. This amide group is derived from cyclohexylcarboxylic acid, and bonded to cyclohexane ring.
Thus, the structure corresponding to given name is,
Figure 4
The structure corresponding to the given name is drawn in Figure 4.
(e)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is
Explanation of Solution
The given name indicates that compound contains ester (name ends with -ate) as the functional group, and an formate group is bonded to a isopropylgroup
Thus, the structure corresponding to the given name is,
Figure 5
The structure corresponding to the given name is drawn in Figure 5.
(f)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains amide (name ends with -amide) as the functional group. This amide group is derived from pentanoic acid, and
Thus, the structure corresponding to given name is,
Figure 6
The structure corresponding to the given name is drawn in Figure 6.
(g)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains cyano (name ends with -nitrile) as the functional group, and heptane as the longest carbon chain with one methyl substitution at
Thus, the structure corresponding to given name is,
Figure 7
The structure corresponding to the given name is drawn in Figure 7.
(h)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains ester (name ends with -ate) as the functional group, and an acetate group is bonded to a vinyl group
Thus, the structure corresponding to the given name is,
Figure 8
The structure corresponding to the given name is drawn in Figure 8.
(i)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains anhydride (name ends with -anhydride) as the functional group. This anhydride compound is derived from benzoic acid and propanoic acid.
Thus, the structure corresponding to the given name is,
Figure 9
The structure corresponding to the given name is drawn in Figure 9.
(j)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains acid chloride (name ends with -yl chloride) as the functional group, and hexane as the longest carbon chain with one methyl substitution at
Thus, the structure corresponding to the given name is,
Figure 10
The structure corresponding to the given name is drawn in Figure 10.
(k)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains ester (name ends with –ate) as the functional group, and butane as the longest carbon chain with one octyl substitution as
Thus, the structure corresponding to the given name is,
Figure 11
The structure corresponding to the given name is drawn in Figure 11.
(l)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains amide (name ends with -amide) as the functional group. This amide group is derived from formic acid, and bonded to two benzyl groups.
Thus, the structure corresponding to the given name is,
Figure 12
The structure corresponding to the given name is drawn in Figure 12.
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Chapter 22 Solutions
Organic Chemistry
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