Concept explainers
(a)
Interpretation: The percent by mass of M in
Concept introduction: Grignard reagent is an
To determine: The percent by mass of M in
(a)
Answer to Problem 159IP
Answer
The mass percent of M in
Explanation of Solution
Explanation
Given
Electronic configuration of
So,
In periodic table atomic number is found to be of the element Zinc.
The molar mass of Zinc is
The molar mass of compound
The molar mass of carbon is
The molar mass of hydrogen is
The molar mass of Zinc is
The molar mass of Bromine is
The molar mass of compound
Therefore the total molar mass of compound
The mass percent of M in
Substitute the value of the molar mass of M and total molar mass of compound, to calculate percent by mass of M in
Therefore, the mass percent of M in
Conclusion
The mass percent of M in
(b)
Interpretation: The percent by mass of M in
Concept introduction: Grignard reagent is an organometallic compound which is prepared by treating magnesium or metal atom with a strong acid. The Grignard reaction is defined as an organometallic reaction in which the vinyl, alkyl and aryl-metal halides were added to a carbonyl carbon atom and form an aldehyde or ketone.
To determine: The hybridization of the starred carbon atom in the given figure changed from reactants to products.
(b)
Answer to Problem 159IP
Answer
The hybridization of the starred carbon atom shown in Figure 1 is changed from
Explanation of Solution
Explanation
The given reaction is,
Figure 1
In the given reaction the reactant contains carbonyl group having double bonded oxygen atom hence, the hybridization of the starred carbon in the reactant is
Conclusion
The hybridization of the starred carbon atom shown in Figure 1 is changed from
(c)
Interpretation: The percent by mass of M in
Concept introduction: Grignard reagent is an organometallic compound which is prepared by treating magnesium or metal atom with a strong acid. The Grignard reaction is defined as an organometallic reaction in which the vinyl, alkyl and aryl-metal halides were added to a carbonyl carbon atom and form an aldehyde or ketone.
To determine: The systematic name of the product.
(c)
Answer to Problem 159IP
Answer
The systematic name of the product is
Explanation of Solution
Explanation
The given compound is,
Figure 2
The longest carbon chain contains six carbon atoms numbered from the nearest functional group with an alcohol group present on third carbon. Hence, the root name of the compound is hexanol. It also contains two methyl groups present on third and fourth carbon atom respectively. Hence, the name of the compound is
Conclusion
The systematic name of the product shown in Figure 2 is
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Chapter 22 Solutions
Chemistry
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