Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Textbook Question
Chapter 22, Problem 141CWP
a. Name each of the following alcohols.
b. Name each of the following alcohols, including the stereochemistry if cis-trans isomers are possible.
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1.
a. Draw the structures of the two isomers of dibromoethane. Name them by the IUPAC system.
b. Draw out the structures of the two isomers of iodopropane. Name them by the IUPAC system.
c. Draw the structures of the three isomers of dichloroethene. Name each one by the IUPAC system, indicating stereochemistry where relevant.
This is no multiple questions please answer only draw structure all
C. Nomenclature of Cylic Alkanes:
If a ring is present in a molecule, the ring is almost always considered the parent chain.
Use the word cyclo as a prefix before the alkane name to indicate it is a cyclic parent chain
Number the carbons that bear substituents starting with one, and number around the ring towards the closest carbon
that bears another substituent group to give all substituents lowest possible numbering.
If there are two or more substituents, use alphabetical order to determine where to start numbering.
Critical Thinking Question (CTQ):
11. Give the correct IUPAC name for the remaining three compounds below.
H,C
CH-CH,
l-isopropyl-3-methylcycloherane
12. Draw the structures that correspond to the following names:
a. 3-ethylheptane
b. 1,1-diethylcyclopropane
c. 4-sec-butyl-1-isobutyl-2-methylcylcohexane
13. Mono-substituted cycloalkanes do not include the "1" locant. Thus, 1-methylcyclohexane is inaccurate.
Draw methylcyclohexane; explain why adding a locant does not add…
Chapter 22 Solutions
Chemistry
Ch. 22 - What is a hydrocarbon? What is the difference...Ch. 22 - Prob. 2RQCh. 22 - What are aromatic hydrocarbons? Benzene exhibits...Ch. 22 - Summarize the nomenclature rules for alkanes,...Ch. 22 - What functional group distinguishes each of the...Ch. 22 - Distinguish between isomerism and resonance....Ch. 22 - Prob. 7RQCh. 22 - Prob. 8RQCh. 22 - Prob. 9RQCh. 22 - Prob. 10RQ
Ch. 22 - Prob. 11RQCh. 22 - Describe the structural differences between DNA...Ch. 22 - Prob. 1QCh. 22 - Prob. 2QCh. 22 - Prob. 3QCh. 22 - Prob. 4QCh. 22 - Prob. 5QCh. 22 - Prob. 6QCh. 22 - Prob. 7QCh. 22 - Give an example reaction that would yield the...Ch. 22 - Prob. 9QCh. 22 - Prob. 10QCh. 22 - Prob. 11QCh. 22 - Prob. 12QCh. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Draw all the structural isomers for C8H18 that...Ch. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Draw the structural formula for each of the...Ch. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Name each of the following cyclic alkanes, and...Ch. 22 - Prob. 23ECh. 22 - Draw the structures for two examples of...Ch. 22 - Name each of the following alkenes. a. CH2 = CH ...Ch. 22 - Name each of the following alkenes or alkynes. a....Ch. 22 - Prob. 27ECh. 22 - Give the structure for each of the following. a....Ch. 22 - Prob. 29ECh. 22 - Cumene is the starting material for the industrial...Ch. 22 - Name each of the following. a. b. CH3CH2CH2CCl3 c....Ch. 22 - Prob. 32ECh. 22 - There is only one compound that is named...Ch. 22 - Prob. 34ECh. 22 - Prob. 35ECh. 22 - Prob. 36ECh. 22 - Draw all the structural isomers of C5H10. Ignore...Ch. 22 - Prob. 38ECh. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all the structural and geometrical (cistrans)...Ch. 22 - Draw all structural and geometrical (cistrans)...Ch. 22 - Prob. 42ECh. 22 - Prob. 43ECh. 22 - Prob. 44ECh. 22 - If one hydrogen in a hydrocarbon is replaced by a...Ch. 22 - There are three isomers of dichlorobenzene, one of...Ch. 22 - Identify each of the following compounds as a...Ch. 22 - Prob. 48ECh. 22 - Mimosine is a natural product found in large...Ch. 22 - Minoxidil (C9H15N5O) is a compound produced by...Ch. 22 - For each of the following alcohols, give the...Ch. 22 - Prob. 52ECh. 22 - Prob. 53ECh. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Prob. 56ECh. 22 - Prob. 57ECh. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Super glue contains methyl cyanoacrylate, which...Ch. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Prob. 79ECh. 22 - Prob. 80ECh. 22 - Prob. 81ECh. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Aspartame, the artificial sweetener marketed under...Ch. 22 - Prob. 86ECh. 22 - Prob. 87ECh. 22 - Draw the structures of the tripeptides glyalaser...Ch. 22 - Prob. 89ECh. 22 - Prob. 90ECh. 22 - Give an example of amino acids that could give...Ch. 22 - What types of interactions can occur between the...Ch. 22 - Prob. 93ECh. 22 - Prob. 94ECh. 22 - Prob. 95ECh. 22 - Prob. 96ECh. 22 - Prob. 97ECh. 22 - Prob. 98ECh. 22 - Prob. 99ECh. 22 - Prob. 100ECh. 22 - Prob. 101ECh. 22 - Prob. 102ECh. 22 - Prob. 103ECh. 22 - Prob. 104ECh. 22 - Prob. 105ECh. 22 - Prob. 106ECh. 22 - Prob. 107ECh. 22 - Prob. 108ECh. 22 - The base sequences in mRNA that code for certain...Ch. 22 - Prob. 110ECh. 22 - Prob. 111AECh. 22 - Prob. 112AECh. 22 - Prob. 113AECh. 22 - Prob. 114AECh. 22 - Prob. 115AECh. 22 - Prob. 116AECh. 22 - Explain why methyl alcohol is soluble in water in...Ch. 22 - Prob. 118AECh. 22 - Prob. 119AECh. 22 - Prob. 120AECh. 22 - Prob. 121AECh. 22 - Prob. 122AECh. 22 - Prob. 123AECh. 22 - Prob. 124AECh. 22 - Prob. 125AECh. 22 - Prob. 126AECh. 22 - Prob. 127AECh. 22 - Prob. 128AECh. 22 - Prob. 129AECh. 22 - a. Use bond energies (see Table 3-3) to estimate H...Ch. 22 - Prob. 131AECh. 22 - Prob. 132AECh. 22 - All amino acids have at least two functional...Ch. 22 - Prob. 134AECh. 22 - Prob. 135AECh. 22 - In glycine, the carboxylic acid group has Ka = 4.3...Ch. 22 - Name each of the following alkanes. a....Ch. 22 - Prob. 138CWPCh. 22 - Name each of the following cyclic alkanes. a. b....Ch. 22 - Name each of the following alkenes and alkynes. a....Ch. 22 - a. Name each of the following alcohols. b. Name...Ch. 22 - Prob. 142CWPCh. 22 - Prob. 143CWPCh. 22 - Prob. 144CWPCh. 22 - Prob. 145CPCh. 22 - Prob. 146CPCh. 22 - Prob. 147CPCh. 22 - Consider a sample of a hydrocarbon at 0.959 atm...Ch. 22 - Prob. 149CPCh. 22 - Prob. 150CPCh. 22 - Prob. 151CPCh. 22 - Prob. 152CPCh. 22 - Prob. 153CPCh. 22 - Prob. 154CPCh. 22 - Prob. 155CPCh. 22 - Alcohols are very useful starting materials for...Ch. 22 - A chemical breathalyzer test works because ethanol...Ch. 22 - Estradiol is a female hormone with the following...Ch. 22 - Prob. 159IPCh. 22 - Prob. 160IPCh. 22 - Prob. 161MPCh. 22 - Prob. 162MP
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- 1. Name each compound and determine the relationship between the pairs of compounds. a. Name: b. Name: Relationship between structures above: Conformational isomer or Structural isomer 2. Name: 3. Is the following structure the cis stereoisomer or the trans stereoisomer?arrow_forwardWhich of the following is true of conformational isomers? O A. They arise from rotation about single bonds. B. They cannot be isolated under ordinary conditions of temperature and pressure. O C. They have the same structural formulas D. all of these E. none of thesearrow_forwardHexane and cyclohexane are examples of two molecules that are. A . Constitutional Isomers B. cis - trans isomers C. identical D. enanitiomers E . Unrelated with different formulasarrow_forward
- Look at a cyclohexane model:a. Mark the axial bonds. Hold carbon atoms 1, 2, 3, 4, 5, and 6 firmly and flip up carbon 4. What is the resulting conformation? b. Then holding carbons 2, 3, 4, 5, and 6 firmly, flip down carbon What is now the resulting conformation?arrow_forwardSome alkenes have cis-trans isomers because a. the carbon atoms in the double bond are free to rotate. b. one of the carbon atoms in the double bond has two identical groups attached to it. c. all of the carbon atoms in the compound are rigid and cannot rotate. d. each of the carbon atoms in the double bond has four different groups attached to it. e. the carbon atoms in the double bond cannot rotate.arrow_forward1. Identify the SYSTEMATIC name of the aliphatic hydrocarbon a. 1-pentenyicyclopentane b. 1-cyclopentylpent-2-yne c. 1-pentenecyclopent-2-yne d. 1-pentenyicyclopentane 2. Identify the SYSTEMATIC name of the aliphatic hydrocarbon a. Trans-1,2-propylcyclopropane b. Trans-1,2-diisopropylcyclopropane c. Cis-1,2-propylcyclopropane d. Cis-1,2-diisopropylcyclopropane 3. Identify the SYSTEMATIC name of the aliphatic hydrocarbon 3,10-dimethyl-2-decacen-6-yne 3,10-dimethyl-2-dodocen-6-yne 3,10-dimethyl-10-decacen-6-yne d. 3,10-dimethyl-10-dodocen-6-yne a. b. C. 4. Identify which type of isomer the following structures represent HO a. Skeletal Isomer b. E/Z isomer c. Cis/Trans isomer OH OH d. Positional isomer 5. Identify which type of isomer the following structures represent a. Skeletal Isomer Br b. E/Z isomer c Cis/Trans isomer Br d. Positional isomerarrow_forward
- 6. Any organic compound that contains a benzene ring or similar feature. O a. addition reaction Ob. aliphatic compound Oc. alkene d. alkyne Oe. aromatic hydrocarbon Of. hydration g. hydrogenation h. monomer Oi. phenyl group j. polycyclic aromatic hydrocarbon k. polymer I. unsaturated hydrocarbonarrow_forwardB) Write a structural formula that corresponds to the molecular formula CH,O and is a. acyclic b. carbocyclic c. heterocyclicarrow_forward13. Ethylethanoate and butanoic acid can be classified as A. positional isomers B. chain isomers C. functional isomers D. stereoisomers 14. Which of the following pairs are positional isomers A. trans-1,4-dichlorocyclohexane, cis-1,3-dichlorocyclopentane B. trans 1,4-dichlorocyclohexane, cis-1,4-dichlorocyclohexane C. 2-pentanol, Cyclopentanol D. 1,2-cycohexanediol, 1,3-cycohexanediol 15. Which of the following compounds will have zero dipole moment? A. cis-1,2-dibromoethylene B. 1,1-dibromoethylene C. trans-1,2-dibromoethylene D. all of these 16. Which of the following is not aromatic: A. cyclopentadienyl cation B. cyclopentadienyl anion C. Cyclopropenyl cation D. Cycloheptatrienyl cation 17. Which of the following compounds containing lone pair has the least tendency to donate its electrons? A. the lone pair in pyridine B. the lone pair in furan C. the lone pair in pyrole D. the lone pair in thiophenearrow_forward
- 7. Which of the following structures is a meso form? (circle your answer) OH Br Br ÕH CIarrow_forwardXIII. Draw skeletal structures corresponding to the following names. a. 1-chloro-2-isopropylcyclopentane b. 3,5-dicyclohexylnonane c. 3,3-Diethyl-2,5-dimethylnonane d. 4-Isopropyl-3-methylheptanearrow_forward7. Which of the following best describe the structure of the carbon atom? a. Its atomic structure and valence number of 4 makes it able to form4 covalent bonds with atoms of other elements and another carbon atom. b. Its atomic structure allows many types of arrangements that leads to a short and long straight and branched chained structures. c. both a and b d. none of these 8. Which of the following best explains the characteristics of carbon atom? a. Its valence number of 4 results to a full outer energy by forming four covalent bonds. b. Carbon atoms can form single, double or triple covalent bonds with other carbon atoms. c. It has four valence bonds, and the energy required to make or break a bond is at an appropriate level for building molecules, which are stable and reactive. d. All of the abovearrow_forward
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