The product formed from the reduction of D-idose is to be represented. Concept Introduction: Sodium borohydride is a strong reducing agent. The carbonyl group in aldehydes and ketones can be reduced to an alcohol group by the compound sodium borohydride. The product formed by the reduction is a polyalcohol and also known as alditol.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.6, Problem 12P

a)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-idose is to be represented.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldehydes and ketones can be reduced to an alcohol group by the compound sodium borohydride. The product formed by the reduction is a polyalcohol and also known as alditol.

b)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-sorbose is to be outlined.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldoses and ketones can be reduced to an alcohol group by the compound sodium borohydride with hydrolysis. The product formed by the reduction is a polyalcohol and also known as alditol.

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Complete the reaction in the fewest number of steps as possible, Draw all intermediates (In the same form as the picture provided) and provide all reagents.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.6, Problem 12P

a)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-idose is to be represented.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldehydes and ketones can be reduced to an alcohol group by the compound sodium borohydride. The product formed by the reduction is a polyalcohol and also known as alditol.

b)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-sorbose is to be outlined.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldoses and ketones can be reduced to an alcohol group by the compound sodium borohydride with hydrolysis. The product formed by the reduction is a polyalcohol and also known as alditol.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.6, Problem 12P

a)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-idose is to be represented.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldehydes and ketones can be reduced to an alcohol group by the compound sodium borohydride. The product formed by the reduction is a polyalcohol and also known as alditol.

b)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-sorbose is to be outlined.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldoses and ketones can be reduced to an alcohol group by the compound sodium borohydride with hydrolysis. The product formed by the reduction is a polyalcohol and also known as alditol.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.6, Problem 12P

a)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-idose is to be represented.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldehydes and ketones can be reduced to an alcohol group by the compound sodium borohydride. The product formed by the reduction is a polyalcohol and also known as alditol.

b)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-sorbose is to be outlined.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldoses and ketones can be reduced to an alcohol group by the compound sodium borohydride with hydrolysis. The product formed by the reduction is a polyalcohol and also known as alditol.

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Answer 5

Chapter 21.6, Problem 12P

a)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-idose is to be represented.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldehydes and ketones can be reduced to an alcohol group by the compound sodium borohydride. The product formed by the reduction is a polyalcohol and also known as alditol.

b)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-sorbose is to be outlined.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldoses and ketones can be reduced to an alcohol group by the compound sodium borohydride with hydrolysis. The product formed by the reduction is a polyalcohol and also known as alditol.

Answer 6

Chapter 21.6, Problem 12P

a)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-idose is to be represented.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldehydes and ketones can be reduced to an alcohol group by the compound sodium borohydride. The product formed by the reduction is a polyalcohol and also known as alditol.

Answer 7

Chapter 21.6, Problem 12P

a)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-idose is to be represented.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldehydes and ketones can be reduced to an alcohol group by the compound sodium borohydride. The product formed by the reduction is a polyalcohol and also known as alditol.

Answer 8

b)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-sorbose is to be outlined.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldoses and ketones can be reduced to an alcohol group by the compound sodium borohydride with hydrolysis. The product formed by the reduction is a polyalcohol and also known as alditol.

Answer 9

b)

Interpretation Introduction

Interpretation:

The product formed from the reduction of D-sorbose is to be outlined.

Concept Introduction:

Sodium borohydride is a strong reducing agent. The carbonyl group in aldoses and ketones can be reduced to an alcohol group by the compound sodium borohydride with hydrolysis. The product formed by the reduction is a polyalcohol and also known as alditol.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21.1 - Prob. 1P Ch. 21.2 - Prob. 2P Ch. 21.2 - Prob. 3P Ch. 21.3 - Prob. 4P Ch. 21.3 - Prob. 5P Ch. 21.3 - Prob. 6P Ch. 21.4 - Prob. 7P Ch. 21.4 - Prob. 8P Ch. 21.5 - Prob. 9P Ch. 21.5 - Prob. 10P

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Chapter 21 Solutions