Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
7th Edition
ISBN: 9780134240152
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 21.4, Problem 7P
Interpretation Introduction
Interpretation:
A sugar that is the
Concept Introduction:
Epimers are the monosaccharide which differs in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,
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The Concept of Aromaticity
21.15 State the number of 2p orbital electrons in each molecule or ion.
(a)
(b)
(e)
(f)
(c)
(d)
(h)
(i)
DA
(k)
21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the
Hückel criteria? Which, if planar, would be antiaromatic?
21.17 Which of the following structures are considered aromatic according to the Hückel
criteria?
---0-0
(a)
(b)
(c)
(d)
(e)
(h)
H
-H
.8.0-
21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a
heteroatom?
1. Show the steps necessary to make 2-methyl-4-nonene using a
Wittig reaction. Start with triphenylphosphine and an alkyl
halide. After that you may use any other organic or inorganic
reagents.
2. Write in the product of this reaction:
CH3
CH₂
(C6H5)₂CuLi
H₂O+
3. Name this compound properly, including stereochemistry.
H₂C
H3C
CH3
OH
4. Show the step(s) necessary to transform the compound on the
left into the acid on the right.
Bri
CH2
5. Write in the product of this
LiAlH4
Br
H₂C
OH
Chapter 21 Solutions
Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
Ch. 21.1 - Prob. 1PCh. 21.2 - Prob. 2PCh. 21.2 - Prob. 3PCh. 21.3 - Prob. 4PCh. 21.3 - Prob. 5PCh. 21.3 - Prob. 6PCh. 21.4 - Prob. 7PCh. 21.4 - Prob. 8PCh. 21.5 - Prob. 9PCh. 21.5 - Prob. 10P
Ch. 21.5 - Prob. 11PCh. 21.6 - Prob. 12PCh. 21.6 - Prob. 13PCh. 21.6 - Prob. 14PCh. 21.7 - Prob. 15PCh. 21.8 - Prob. 16PCh. 21.9 - Prob. 18PCh. 21.10 - Prob. 20PCh. 21.10 - Prob. 21PCh. 21.10 - Prob. 22PCh. 21.11 - Prob. 24PCh. 21.11 - Prob. 25PCh. 21.15 - Prob. 27PCh. 21.16 - Prob. 28PCh. 21.17 - Prob. 29PCh. 21.18 - Refer to Figure 20.5 to answer the following...Ch. 21 - Prob. 31PCh. 21 - Prob. 32PCh. 21 - Prob. 33PCh. 21 - Prob. 34PCh. 21 - Prob. 35PCh. 21 - Prob. 36PCh. 21 - Prob. 37PCh. 21 - Prob. 38PCh. 21 - Prob. 39PCh. 21 - Prob. 40PCh. 21 - Prob. 41PCh. 21 - Prob. 42PCh. 21 - Prob. 43PCh. 21 - Prob. 44PCh. 21 - The 1H NMR spectrum of D-glucose in D2O exhibits...Ch. 21 - Prob. 46PCh. 21 - Prob. 47PCh. 21 - Prob. 48PCh. 21 - Prob. 49PCh. 21 - Prob. 50PCh. 21 - Prob. 51PCh. 21 - Prob. 52PCh. 21 - Prob. 53PCh. 21 - Prob. 54PCh. 21 - Prob. 55PCh. 21 - A hexose is obtained when the residue of a shrub...Ch. 21 - Prob. 57PCh. 21 - Prob. 58PCh. 21 - Prob. 59PCh. 21 - Prob. 60PCh. 21 - Prob. 61PCh. 21 - Prob. 62PCh. 21 - Prob. 63PCh. 21 - Prob. 64PCh. 21 - Prob. 65PCh. 21 - Prob. 66P
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