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Chapter 21, Problem 58P

a)

Interpretation Introduction

Interpretation:

The structure of βD-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

b)

Interpretation Introduction

Interpretation:

The structure of αD-idopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

c)

Interpretation Introduction

Interpretation:

The structure of αD-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

d)

Interpretation Introduction

Interpretation:

The structure of βD-psicofuranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

e)

Interpretation Introduction

Interpretation:

The structure of βL-talopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection. Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose. A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

f)

Interpretation Introduction

Interpretation:

The structure of αL-tagatopyranose is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

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Chapter 21 Solutions

Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)

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