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Chapter 21.11, Problem 24P
Interpretation Introduction

Interpretation:

The products (in chair conformers formed), from the reaction of β- D-galactose with ethanol and HCl have to be drawn.

Concept Introduction:

Sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise, β sugar.  Hydroxyl group of α-sugar present on right side in Fischer projection is represented down in Haworth projection and at axial position in chair conformation.

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1. Show the steps necessary to make 2-methyl-4-nonene using a Wittig reaction. Start with triphenylphosphine and an alkyl halide. After that you may use any other organic or inorganic reagents. 2. Write in the product of this reaction: CH3 CH₂ (C6H5)₂CuLi H₂O+
3. Name this compound properly, including stereochemistry. H₂C H3C CH3 OH 4. Show the step(s) necessary to transform the compound on the left into the acid on the right. Bri CH2 5. Write in the product of this LiAlH4 Br H₂C OH
What are the major products of the following reaction? Please provide a detailed explanation and a drawing to show how the reaction proceeds.

Chapter 21 Solutions

Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)

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