ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 21.2, Problem 8P
Interpretation Introduction

Interpretation:

The values of equilibrium constant K while reacting ethoxide with ethyl acetoacetate and diethyl malonate is to be estimated.

Concept Introduction:

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The equilibrium constant is a parameter that describes the relation between the concentration of the reactantspecies and the productspecies at equilibrium stage.

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The value of pKa is used to calculate the equilibrium constant K by the formula, Keq=10ΔpKa. Here, ΔpKa=pKa(product)pKa(reactant).

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 21 Solutions

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