ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 21, Problem 49P
Interpretation Introduction

Interpretation:

The reaction that shows the formation of the given compounds by taking 3pentanone as a starting reagent is to be determined.

Concept Introduction:

The γ-lactones are formed by the intramolecular cyclization of the carboxylic esters.

Epoxides are the cyclic compounds which provide a route for the preparation of γ-lactones.

The compounds containing carbonyl groups are attacked by these epoxides which cause the alkylation at the alpha position of the carbonyl compound.

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1. Which one(s) of these can be oxidized with CrO3 ? (could be more than one) a) triphenylmethanol b) 2-pentanol c) Ethyl alcohol d) CH3 2. Write in all the product(s) of this reaction. Label them as "major" or "minor". 2-methyl-2-hexanol H2SO4, heat
3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)

Chapter 21 Solutions

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