EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Textbook Question
Chapter 2.1, Problem 2.4P
Classify each micronutrient in Figure 2.2 as a metal, nonmetal, or metalloid.
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 2 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 2.1 - Give the symbol for each element. a. calcium, a...Ch. 2.1 - Give the name corresponding to each element...Ch. 2.1 - Locate each element in the periodic table and...Ch. 2.1 - Classify each micronutrient in Figure 2.2 as a...Ch. 2.1 - Identify the elements used ineach example of...Ch. 2.1 - Identify the elements in each chemical formula,...Ch. 2.1 - Prob. 2.7PCh. 2.2 - Prob. 2.8PCh. 2.2 - Prob. 2.9PCh. 2.2 - For the given atom: (a) determine the number of...
Ch. 2.2 - How many protons, neutrons, and electrons are...Ch. 2.2 - What is the mass number of an atom that contains...Ch. 2.3 - For each atom give the following information: [1]...Ch. 2.3 - Magnesium has three isotopes that contain 12, 13,...Ch. 2.3 - Prob. 2.15PCh. 2.3 - Calculate the atomic weight of each element given...Ch. 2.4 - Prob. 2.17PCh. 2.4 - Prob. 2.18PCh. 2.4 - Identify the element fitting each description. an...Ch. 2.4 - Identify each highlighted element in the periodic...Ch. 2.5 - How many electrons are present in each shell,...Ch. 2.6 - What element has each electronic configuration? a....Ch. 2.6 - What element(s) in the first and second period fit...Ch. 2.6 - Draw an orbital diagram for each element; (a)...Ch. 2.6 - Give the electronic configuration for each element...Ch. 2.7 - Prob. 2.26PCh. 2.7 - Determine the number of valence electrons and give...Ch. 2.7 - Prob. 2.28PCh. 2.7 - Give the electron-dot symbol for each element: (a)...Ch. 2.8 - Which element in each pair has the larger atomic...Ch. 2.8 - Prob. 2.31PCh. 2.8 - (a) Which of the indicated atoms has the smaller...Ch. 2 - Identify the elements used in each example of...Ch. 2 - Write a chemical formula for each example of...Ch. 2 - Give the name of the elements in each group of...Ch. 2 - What element(s) are designated by each symbol or...Ch. 2 - Does each chemical formula represent an element or...Ch. 2 - Identify the elements in each chemical formula and...Ch. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Give all of the terms that apply to each...Ch. 2 - Give all of the terms that apply to each...Ch. 2 - Give the following information about the atom...Ch. 2 - Give the following information about the atom...Ch. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - Label each region on the periodic table. Noble...Ch. 2 - Identify each highlighted element in the periodic...Ch. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - Prob. 2.51PCh. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - Prob. 2.55PCh. 2 - Prob. 2.56PCh. 2 - How many protons, neutrons, and electrons are...Ch. 2 - Give the number of protons, neutrons, and...Ch. 2 - Write the element symbol that fits each...Ch. 2 - Write the element symbol that fits each...Ch. 2 - Calculate the atomic weight of silver, which has...Ch. 2 - Calculate the atomic weight of antimony, which has...Ch. 2 - Prob. 2.63PCh. 2 - What is the maximum number of electrons that can...Ch. 2 - Prob. 2.65PCh. 2 - Use an orbital diagram to write the electronic...Ch. 2 - Prob. 2.67PCh. 2 - For each element in Problem 2.66: Write out the...Ch. 2 - Prob. 2.69PCh. 2 - Prob. 2.70PCh. 2 - Give the total number of electrons, the number of...Ch. 2 - Give the total number of electrons, the number of...Ch. 2 - Prob. 2.73PCh. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - Prob. 2.76PCh. 2 - Prob. 2.77PCh. 2 - Prob. 2.78PCh. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - Prob. 2.83PCh. 2 - Prob. 2.84PCh. 2 - Prob. 2.85PCh. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - Rank the atoms in each group in order of...Ch. 2 - Prob. 2.90PCh. 2 - Prob. 2.91PCh. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - Prob. 2.94PCh. 2 - Prob. 2.95PCh. 2 - (a) What is the chemical formula for...Ch. 2 - Answer the following questions about the...Ch. 2 - Platinum is a precious metal used in a wide...Ch. 2 - Prob. 2.99PCh. 2 - Answer the following questions about the...Ch. 2 - Prob. 2.101CPCh. 2 - Prob. 2.102CP
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- Show the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forwardDraw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forward
- Draw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forwardPart I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forward
- what are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward
- 19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forward
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