
(a)
Interpretation:
From the given spectra, the structure of the molecule is to be determined and mechanism is to be drawn.
Concept introduction:
Various spectroscopies are the primary method for determining the structure of compounds. If the molecule is not too large or complex, the determination should be very accurate. These are simply done and rapid. For overlapping information, they can be combined. According to the structure of the molecule, the molecules absorb specific
(b)
Interpretation:
From the given spectra, the structure of the molecule is to be determined and mechanism is to be drawn.
Concept introduction:
Various spectroscopies are the primary method for determining the structure of compounds. If the molecule is not too large or complex, the determination should be very accurate. These are simply done and rapid. For overlapping information, they can be combined. According to the structure of the molecule, the molecules absorb specific frequencies of light. The IR spectroscopy theory utilizes this concept. Mass spectroscopy (MS) measures the mass to charge the ratio of ions. In order to determine the structure of the molecule, Proton nuclear magnetic resonance (1H NMR) is used.
(c)
Interpretation:
From the given spectra, the structure of the molecule is to be determined and mechanism is to be drawn.
Concept introduction:
Various spectroscopies are the primary method for determining the structure of compounds. If the molecule is not too large or complex, the determination should be very accurate. These are simply done and rapid. For overlapping information, they can be combined. According to the structure of the molecule, the molecules absorb specific frequencies of light. The IR spectroscopy theory utilizes this concept. Mass spectroscopy (MS) measures the mass to charge the ratio of ions. In order to determine the structure of the molecule, Proton nuclear magnetic resonance (1H NMR) is used.

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Chapter 21 Solutions
EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
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- Draw the stepwise mechanism for the reactionsarrow_forwardPart I. a) Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone (3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forward3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
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