(a) Interpretation: The mechanism and major organic product for the given reaction is to be drawn. Concept introduction: The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

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Answer 1

Question

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

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Answer 2

Question

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

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Answer 3

Question

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

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Answer 4

Question

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Answer 6

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Answer 7

Chapter 21, Problem 21.54P

Interpretation Introduction

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The cyclic amide, in an acidic condition, undergoes hydrolysis and forms a compound having functional groups as carboxylic acid and amine. As the reaction occurs in an acidic condition, the amine nitrogen remains protonated.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

(a) Interpretation: The mechanism and major organic product for the given reaction is to be drawn. Concept introduction: The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

(a) Interpretation: The mechanism and major organic product for the given reaction is to be drawn. Concept introduction: The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.

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Chapter 21 Solutions

(a)

Interpretation:

The mechanism and major organic product for the given reaction is to be drawn.

Concept introduction:

The primary amide, in an acidic condition, undergoes hydrolysis and forms the corresponding carboxylic acid by removing ammonia as the leaving group.