(a) Interpretation: To draw the complete detailed mechanism and predict the major product Concept introduction: Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Question

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.1P

Interpretation Introduction

(a)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

This is an alcoholysis reaction. First step includes nucleophilic addition of alcohol to electrophilic carbon of acid chloride to produce tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another alcohol molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed by loss of Cl^- group from the intermediate giving an ester.

Conclusion

This is an alcoholysis reaction between an acid chloride and alcohol to give an ester.

Interpretation Introduction

(b)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 2

Explanation of Solution

This is a hydrolysis reaction. First step includes nucleophilic addition of water to electrophilic carbon of acid chloride to produce a tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another water molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed back by the loss of Cl^- group from the intermediate giving carboxylic acid.

Conclusion

This is a hydrolysis reaction between an acid chloride and water to give carboxylic acid.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.1P

Interpretation Introduction

(a)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

This is an alcoholysis reaction. First step includes nucleophilic addition of alcohol to electrophilic carbon of acid chloride to produce tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another alcohol molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed by loss of Cl^- group from the intermediate giving an ester.

Conclusion

This is an alcoholysis reaction between an acid chloride and alcohol to give an ester.

Interpretation Introduction

(b)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 2

Explanation of Solution

This is a hydrolysis reaction. First step includes nucleophilic addition of water to electrophilic carbon of acid chloride to produce a tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another water molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed back by the loss of Cl^- group from the intermediate giving carboxylic acid.

Conclusion

This is a hydrolysis reaction between an acid chloride and water to give carboxylic acid.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.1P

Interpretation Introduction

(a)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

This is an alcoholysis reaction. First step includes nucleophilic addition of alcohol to electrophilic carbon of acid chloride to produce tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another alcohol molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed by loss of Cl^- group from the intermediate giving an ester.

Conclusion

This is an alcoholysis reaction between an acid chloride and alcohol to give an ester.

Interpretation Introduction

(b)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 2

Explanation of Solution

This is a hydrolysis reaction. First step includes nucleophilic addition of water to electrophilic carbon of acid chloride to produce a tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another water molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed back by the loss of Cl^- group from the intermediate giving carboxylic acid.

Conclusion

This is a hydrolysis reaction between an acid chloride and water to give carboxylic acid.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.1P

Interpretation Introduction

(a)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

This is an alcoholysis reaction. First step includes nucleophilic addition of alcohol to electrophilic carbon of acid chloride to produce tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another alcohol molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed by loss of Cl^- group from the intermediate giving an ester.

Conclusion

This is an alcoholysis reaction between an acid chloride and alcohol to give an ester.

Interpretation Introduction

(b)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 2

Explanation of Solution

This is a hydrolysis reaction. First step includes nucleophilic addition of water to electrophilic carbon of acid chloride to produce a tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another water molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed back by the loss of Cl^- group from the intermediate giving carboxylic acid.

Conclusion

This is a hydrolysis reaction between an acid chloride and water to give carboxylic acid.

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Answer 5

Chapter 21, Problem 21.1P

Interpretation Introduction

(a)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

This is an alcoholysis reaction. First step includes nucleophilic addition of alcohol to electrophilic carbon of acid chloride to produce tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another alcohol molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed by loss of Cl^- group from the intermediate giving an ester.

Conclusion

This is an alcoholysis reaction between an acid chloride and alcohol to give an ester.

Interpretation Introduction

(b)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 2

Explanation of Solution

This is a hydrolysis reaction. First step includes nucleophilic addition of water to electrophilic carbon of acid chloride to produce a tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another water molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed back by the loss of Cl^- group from the intermediate giving carboxylic acid.

Conclusion

This is a hydrolysis reaction between an acid chloride and water to give carboxylic acid.

Answer 6

Chapter 21, Problem 21.1P

Interpretation Introduction

(a)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 1

Explanation of Solution

This is an alcoholysis reaction. First step includes nucleophilic addition of alcohol to electrophilic carbon of acid chloride to produce tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another alcohol molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed by loss of Cl^- group from the intermediate giving an ester.

Conclusion

This is an alcoholysis reaction between an acid chloride and alcohol to give an ester.

Answer 7

Chapter 21, Problem 21.1P

Interpretation Introduction

(a)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Answer 8

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 1

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

This is an alcoholysis reaction. First step includes nucleophilic addition of alcohol to electrophilic carbon of acid chloride to produce tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another alcohol molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed by loss of Cl^- group from the intermediate giving an ester.

Answer 13

Conclusion

This is an alcoholysis reaction between an acid chloride and alcohol to give an ester.

Answer 14

Interpretation Introduction

(b)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 2

Explanation of Solution

This is a hydrolysis reaction. First step includes nucleophilic addition of water to electrophilic carbon of acid chloride to produce a tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another water molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed back by the loss of Cl^- group from the intermediate giving carboxylic acid.

Conclusion

This is a hydrolysis reaction between an acid chloride and water to give carboxylic acid.

Answer 15

Interpretation Introduction

(b)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.

Answer 16

Expert Solution

Answer to Problem 21.1P

EBK ORGANIC CHEMISTRY: PRINCIPLES AND M, Chapter 21, Problem 21.1P , additional homework tip 2

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

This is a hydrolysis reaction. First step includes nucleophilic addition of water to electrophilic carbon of acid chloride to produce a tetrahedral intermediate. This intermediate contains an acidic proton which is rapidly deprotonated by another water molecule. This is via proton transfer. Last step is nucleophilic elimination in which the C=O bond is formed back by the loss of Cl^- group from the intermediate giving carboxylic acid.

Answer 21

Conclusion

This is a hydrolysis reaction between an acid chloride and water to give carboxylic acid.

Answer 22

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

(a) Interpretation: To draw the complete detailed mechanism and predict the major product Concept introduction: Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

(a) Interpretation: To draw the complete detailed mechanism and predict the major product Concept introduction: Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

Answer to Problem 21.1P

Explanation of Solution

(b) Interpretation: To draw the complete detailed mechanism and predict the major product Concept introduction: Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.

Answer to Problem 21.1P

Explanation of Solution

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Chapter 21 Solutions

(a)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and alcohol to produce ester is named as alcoholysis reaction. In this reaction, addition of alcohol results in breaking of C-Cl bond.

(b)

Interpretation:

To draw the complete detailed mechanism and predict the major product

Concept introduction:

Reaction between acid chloride and water to produce carboxylic acid is named as hydrolysis reaction. In this reaction, addition of water molecule results in breaking of C-Cl bond.