The major product of the given reaction is to be predicted. Concept introduction: The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, then only one product is formed but if ketone or aldehyde is unsymmetric, then the major product depends on the group that leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows: Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.15P

Interpretation Introduction

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, then only one product is formed but if ketone or aldehyde is unsymmetric, then the major product depends on the group that leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Complete the spectroscopy with structure

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.15P

Interpretation Introduction

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, then only one product is formed but if ketone or aldehyde is unsymmetric, then the major product depends on the group that leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.15P

Interpretation Introduction

Interpretation:

The major product of the given reaction is to be predicted.

Concept introduction:

The synthesis of ester from ketone or aldehyde in presence of CF3CO3H and meta-chloroperbenzoic acid(MCPBA) is called Baeyer Villiger oxidation. In Baeyer villiger oxidation, the oxygen atom from peroxide is inserted between the carbonyl carbon and one of the groups initially bonded to carbonyl carbon. If ketone is symmetric, then only one product is formed but if ketone or aldehyde is unsymmetric, then the major product depends on the group that leaves from the carbonyl carbon. The ability of the leaving group is called migratory aptitude. The order of migratory aptitude is as follows:

Methyl group <primary alkyl group <secondary alkyl group = aryl group <tertiary alkyl group < H.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21, Problem 21.15P

Interpretation Introduction