Organic Chemistry

4th Edition

ISBN: 9780073402772

Author: Janice G. Smith

Publisher: MCG

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Classes Of Functional Groups

Organic Chemistry deals mostly with carbon and hydrogens, also called hydrocarbons, but those groups which replace hydrogen and bonds with carbon to give a characteristic nature, unique of their own, to the hydrocarbon they are attached to, are called fu…

Characteristics Of Functional Groups

In organic chemistry, we encounter a number of special substituent groups which are attached to the hydrocarbon backbone. These groups impart certain characteristics to the molecule of which it is a part of and thus, become the highlight of that particul…

IUPAC Nomenclature

In Chemistry, IUPAC stands for International Union of Pure and Applied Chemistry which suggested a systematic naming approach for the organic and inorganic compounds, as in the beginning stage of nomenclature one single chemical compound was named in man…

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Textbook Question

Chapter 21, Problem 21.71P

Draw a stepwise mechanism f or the following reaction, a key step in the synthesis of the anti-inflammatory drug celecoxib (trade name Celebrex).

Chapter 21, Problem 21.71P, 21.65 Draw a stepwise mechanism f or the following reaction, a key step in the synthesis of the

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Chapter 21, Problem 21.70P

Chapter 21, Problem 21.72P

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Chapter 21 Solutions

Organic Chemistry

Ch. 21 - Rank the following compounds in order of...Ch. 21 - Prob. 21.2P Ch. 21 - Give the IUPAC name for each aldehyde.Ch. 21 - Prob. 21.4P Ch. 21 - Give the IUPAC name for each ketone.Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - The boiling point of is significantly higher than...Ch. 21 - Which carbonyl group in each pair absorbs at a...Ch. 21 - Problem 21.10 Draw the structure of all...

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Draw a stepwise mechanism f or the following reaction, a key step in the synthesis of the anti-inflammatory drug celecoxib (trade name Celebrex).

Solution Summary: The author explains the hydrolysis of both enamines and imines yielding aldehydes and ketones. The stepwise mechanism for the given reaction involves nine steps.

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Chapter 21 Solutions