What reagents are needed to convert each compound to
a. b. c.
(a)
Interpretation: The reagents needed to convert given compound to
Concept introduction: Potassium dichromate is a strong oxidizing agent. Potassium dichromate is used in many organic reactions to oxidize organic compounds. Chromium atom present in Potassium chromate itself gets reduced from oxidation state six to a lower oxidation state and oxidizes the other compound.
Answer to Problem 21.60P
The reagent needed to convert given compound to
Explanation of Solution
The given compound can be converted into
Figure 1
The reagent needed to convert given compound to
(b)
Interpretation: The reagents needed to convert given compound to
Concept introduction: Gilman reagent is an organometallic compound. Gilman reagent is lithium dialkylcuprate that is used to add alkyl group in an organic compound. Gilman reagent reacts with any organic halide and substitute the halide group by an alkyl group.
Answer to Problem 21.60P
The reagents needed to convert given compound to
Explanation of Solution
The given compound can be converted into
Figure 2
The reagents needed to convert given compound to
(c)
Interpretation: The reagents needed to convert given compound to
Concept introduction: Gilman reagent is an organometallic compound. Gilman reagent is lithium dialkylcuprate that is used to add alkyl group in an organic compound. Gilman regent reacts with any organic halide and substitute the halide group by alkyl group.
Answer to Problem 21.60P
The reagent needed to convert given compound to
Explanation of Solution
The given compound can be converted into
Figure 3
The reagent needed to convert given compound to
(d)
Interpretation: The reagents needed to convert given compound to
Concept introduction: When an alkyne reacts with mercury sulfate solution in a strong acidic medium a ketone is formed and this reaction is known as the oxymercuration of alkynes. The oxymercuration of alkyne is a very effective method to convert an alkyne into a ketone.
Answer to Problem 21.60P
The reagent needed to convert given compound to
Explanation of Solution
The given compound can be converted into
Figure 4
The reagent needed to convert given compound to
(e)
Concept introduction: When an alkyne reacts with mercury sulfate solution in a strong acidic medium a ketone is formed and this reaction is known as the oxymercuration of alkynes. The oxymercuration of alkyne is a very effective method to convert an alkyne into a ketone.
Answer to Problem 21.60P
The reagent needed to convert given compound to
Explanation of Solution
The given compound can be converted into
Figure 5
The reagent needed to convert given compound to
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Chapter 21 Solutions
Organic Chemistry
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- 1. CH, CH, - CH,-CH,-CH, + HO 2. H₂C-CH=CH₂ + HBr/H₂O₂ 3. H₂C-CH (OH)-CH₂ + H* 4. Nitrobenzene +? ? anilinearrow_forwardName each alkene: a. CH3CH=CHCH2CH2CH3 b. CH3CH=CH2 c. CH2CH3 l CH2=CHCH2CHCH3arrow_forward18. In the IUPAC name for the following compound, the -Br group is located on carbon number CH;CHCH=CH, Br a. 1 b. 2 С. 3 d. 4arrow_forward
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