Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Textbook Question
Chapter 21, Problem 21.67E
How does the DNA content determine what reactions occur within an organism?
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
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Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter 21 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 21 - What is the principal location of DNA within the...Ch. 21 - Which pentose sugar is present in DNA? In RNA?Ch. 21 - Prob. 21.3ECh. 21 - Prob. 21.4ECh. 21 - Prob. 21.5ECh. 21 - Prob. 21.6ECh. 21 - Prob. 21.7ECh. 21 - Identify the 3 and 5 ends of the DNA segment...Ch. 21 - Prob. 21.9ECh. 21 - Prob. 21.10E
Ch. 21 - Describe the role of hydrogen bonding in the...Ch. 21 - How many total hydrogen bonds would exist between...Ch. 21 - How many total hydrogen bonds would exist between...Ch. 21 - Prob. 21.14ECh. 21 - A strand of DNA has the base sequence GATTCA....Ch. 21 - What is a chromosome? How many chromosomes are in...Ch. 21 - Prob. 21.17ECh. 21 - What is a replication fork?Ch. 21 - Prob. 21.19ECh. 21 - List the steps involved in DNA replication.Ch. 21 - What enzymes are involved in DNA replication?Ch. 21 - In what direction is a new DNA strand formed?Ch. 21 - Prob. 21.23ECh. 21 - Prob. 21.24ECh. 21 - Prob. 21.25ECh. 21 - How does the sugar-phosphate backbone of RNA...Ch. 21 - Compare the secondary structures of RNA and DNA.Ch. 21 - Briefly describe the characteristics and functions...Ch. 21 - Must the ratio of guanine to cytosine be 1:1 in...Ch. 21 - What are the two important regions of a tRNA...Ch. 21 - Prob. 21.31ECh. 21 - In the flow of genetic information, what is meant...Ch. 21 - Prob. 21.33ECh. 21 - Write the base sequence for the mRNA that would be...Ch. 21 - Prob. 21.35ECh. 21 - What is the relationship among exons, introns, and...Ch. 21 - What is a codon?Ch. 21 - For each of the following mRNA codons, give the...Ch. 21 - Describe the experiment that allowed researchers...Ch. 21 - Which of the following statements about the...Ch. 21 - The -chain of hemoglobin is a protein that...Ch. 21 - Prob. 21.42ECh. 21 - Prob. 21.43ECh. 21 - Prob. 21.44ECh. 21 - Prob. 21.45ECh. 21 - Prob. 21.46ECh. 21 - Prob. 21.47ECh. 21 - Prob. 21.48ECh. 21 - Prob. 21.49ECh. 21 - Prob. 21.50ECh. 21 - Prob. 21.51ECh. 21 - Prob. 21.52ECh. 21 - Prob. 21.53ECh. 21 - Prob. 21.54ECh. 21 - Prob. 21.55ECh. 21 - Prob. 21.56ECh. 21 - Prob. 21.57ECh. 21 - Prob. 21.58ECh. 21 - Prob. 21.59ECh. 21 - Genetic engineering shows great promise for the...Ch. 21 - Prob. 21.61ECh. 21 - Prob. 21.62ECh. 21 - Prob. 21.63ECh. 21 - Prob. 21.64ECh. 21 - Prob. 21.65ECh. 21 - Prob. 21.66ECh. 21 - How does the DNA content determine what reactions...Ch. 21 - What would be the ramifications if DNA were single...Ch. 21 - Prob. 21.69ECh. 21 - Prob. 21.70ECh. 21 - Explain the function and importance of each of the...Ch. 21 - Prob. 21.72ECh. 21 - Which base is found in DNA but not in RNA? a....Ch. 21 - Which of the following best describes tRNA? a. It...Ch. 21 - Which of the following is the site of protein...Ch. 21 - In messenger RNA, a codon contains how many...
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