The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified. Concept introduction: Nucleophiles : A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles. Electrophile : An electrophile is a species that accepts a pair of electrons to form a new covalent bond. Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water. Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

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Answer 1

Question

Chapter 20.5, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(b)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(c)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(d)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

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Predict the product(s) of the following reactions. If no reaction, write "NR". a) Cl₂ FeCl3 e) HNO3 H2SO4 b) NO2 CI. HNO3 f) Br Br2 OH H2SO4 HO3S. FeBr3 c) Cl2 g) FeCl3 F d) O₂N Br2 FeBr3 O₂N OH HNO3 CH3 H2SO4

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Answer 2

Question

Chapter 20.5, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(b)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(c)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(d)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

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Answer 3

Question

Chapter 20.5, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(b)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(c)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(d)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

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Answer 4

Question

Chapter 20.5, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(b)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(c)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(d)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

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Answer 5

Chapter 20.5, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(b)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(c)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

(d)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 6

Chapter 20.5, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 7

Chapter 20.5, Problem 12CC

(a)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The given starting compounds and selective reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Nucleophiles: A nucleophile is a more reactant species that affords a pair of electrons to the electrophile or electrophilic center and forms a new covalent bond. The carbon or other hetero atom in a molecule which is bearing negative charge or lone pair of electron is called as nucleophiles.

Electrophile: An electrophile is a species that accepts a pair of electrons to form a new covalent bond.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 20.2 - Prob. 2ATS Ch. 20.2 - Prob. 4ATS Ch. 20.3 - Prob. 5CC Ch. 20.4 - Prob. 6CC Ch. 20.5 - Prob. 7CC Ch. 20.5 - Prob. 2LTS Ch. 20.5 - Prob. 8PTS Ch. 20.5 - Prob. 9ATS Ch. 20.5 - Prob. 10ATS Ch. 20.5 - Prob. 11CC

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Chapter 20 Solutions