Chapter 20, Problem 66PP

(a)

Interpretation Introduction

Interpretation:

The target molecule transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Hydrolysis Reaction:  This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (-C-C-) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which wo alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Meta-chloroperoxybenzoic acid (m-CPBA): This reagent is extremely useful reagent most frequently encountered in the synthesis of epoxides when added to alkenes or alkynes.

Condensation reaction:  The several organic reactions that proceeds in a step-wise reaction to produce the addition product. This type of reaction involves the formation of ammonia, ethanol or mineral acids; it is a versatile class of reaction that can occur in acidic or basic conditions or in the presence of catalyst.

(b).

Interpretation Introduction

Interpretation:

The target molecule transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Hydrolysis Reaction:  This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (-C-C-) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which wo alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Meta-chloroperoxybenzoic acid (m-CPBA): This reagent is extremely useful reagent most frequently encountered in the synthesis of epoxides when added to alkenes or alkynes.

Condensation reaction:  The several organic reactions that proceeds in a step-wise reaction to produce the addition product. This type of reaction involves the formation of ammonia, ethanol or mineral acids; it is a versatile class of reaction that can occur in acidic or basic conditions or in the presence of catalyst.

(c).

Interpretation Introduction

Interpretation:

The target molecule transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Hydrolysis Reaction:  This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (-C-C-) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which wo alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Meta-chloroperoxybenzoic acid (m-CPBA): This reagent is extremely useful reagent most frequently encountered in the synthesis of epoxides when added to alkenes or alkynes.

Condensation reaction:  The several organic reactions that proceeds in a step-wise reaction to produce the addition product. This type of reaction involves the formation of ammonia, ethanol or mineral acids; it is a versatile class of reaction that can occur in acidic or basic conditions or in the presence of catalyst.

(d).

Interpretation Introduction

Interpretation:

The target molecule transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Hydrolysis Reaction:  This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (-C-C-) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which wo alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Meta-chloroperoxybenzoic acid (m-CPBA): This reagent is extremely useful reagent most frequently encountered in the synthesis of epoxides when added to alkenes or alkynes.

Condensation reaction:  The several organic reactions that proceeds in a step-wise reaction to produce the addition product. This type of reaction involves the formation of ammonia, ethanol or mineral acids; it is a versatile class of reaction that can occur in acidic or basic conditions or in the presence of catalyst.

(e).

Interpretation Introduction

Interpretation:

The target molecule transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Hydrolysis Reaction:  This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (-C-C-) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which wo alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Meta-chloroperoxybenzoic acid (m-CPBA): This reagent is extremely useful reagent most frequently encountered in the synthesis of epoxides when added to alkenes or alkynes.

Condensation reaction:  The several organic reactions that proceeds in a step-wise reaction to produce the addition product. This type of reaction involves the formation of ammonia, ethanol or mineral acids; it is a versatile class of reaction that can occur in acidic or basic conditions or in the presence of catalyst.

(f).

Interpretation Introduction

Interpretation:

The target molecule transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Hydrolysis Reaction:  This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (-C-C-) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which wo alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Meta-chloroperoxybenzoic acid (m-CPBA): This reagent is extremely useful reagent most frequently encountered in the synthesis of epoxides when added to alkenes or alkynes.

Condensation reaction:  The several organic reactions that proceeds in a step-wise reaction to produce the addition product. This type of reaction involves the formation of ammonia, ethanol or mineral acids; it is a versatile class of reaction that can occur in acidic or basic conditions or in the presence of catalyst.