Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 20.8, Problem 29CC

(a)

Interpretation Introduction

Interpretation:

The given reagents used to accomplish the target products (major product) transformation should be draw and identified.

Concept Introduction:

Raney nickel is an alloy of aluminum and nickel, which has subsequently had much of the aluminum removed through a leaching process with sodium hydroxide.

Uses of raney nickel: Raney nickel is used most for is its unusable property of reducing C-S bonds to C-H bonds.

Sulfur Nucleophiles:

When a cyclic thio acetal is treated with the Raney nickel through desulfurization process forms alkanes.

Intermediate: Intermediates are formed in the middle of the reaction state which activation energy is very high.

To predict: The reagents used to accomplish the given transformation (a).

(b)

Interpretation Introduction

Interpretation:

The given reagents used to accomplish the target products (major product) transformation should be draw and identified.

Concept Introduction:

Raney nickel is an alloy of aluminum and nickel, which has subsequently had much of the aluminum removed through a leaching process with sodium hydroxide.

Uses of raney nickel: Raney nickel is used most for is its unusable property of reducing C-S bonds to C-H bonds.

Sulfur Nucleophiles:

When a cyclic thio acetal is treated with the Raney nickel through desulfurization process forms alkanes.

Intermediate: Intermediates are formed in the middle of the reaction state which activation energy is very high.

To predict: The reagents used to accomplish the given transformation (a).

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Chapter 20 Solutions

Organic Chemistry

Ch. 20.5 - Prob. 12CCCh. 20.5 - Prob. 13CCCh. 20.5 - Prob. 14CCCh. 20.6 - Prob. 3LTSCh. 20.6 - Prob. 15PTSCh. 20.6 - Prob. 16ATSCh. 20.6 - Prob. 17ATSCh. 20.6 - Prob. 18ATSCh. 20.6 - Prob. 19CCCh. 20.6 - Prob. 20CCCh. 20.6 - Prob. 4LTSCh. 20.6 - Prob. 21PTSCh. 20.6 - Prob. 22ATSCh. 20.6 - Prob. 23ATSCh. 20.6 - Prob. 24ATSCh. 20.7 - Prob. 5LTSCh. 20.7 - Prob. 26PTSCh. 20.7 - Prob. 27ATSCh. 20.7 - Prob. 28CCCh. 20.8 - Prob. 29CCCh. 20.8 - Prob. 30CCCh. 20.9 - Prob. 31CCCh. 20.9 - Prob. 32CCCh. 20.10 - Prob. 33CCCh. 20.10 - Prob. 34CCCh. 20.10 - Prob. 35CCCh. 20.10 - Prob. 36CCCh. 20.10 - Prob. 6LTSCh. 20.10 - Prob. 37PTSCh. 20.10 - Prob. 38ATSCh. 20.10 - Prob. 39ATSCh. 20.11 - Prob. 40CCCh. 20.12 - Prob. 7LTSCh. 20.12 - Prob. 41PTSCh. 20.12 - Prob. 42PTSCh. 20.13 - Prob. 43CCCh. 20 - Prob. 44PPCh. 20 - Prob. 45PPCh. 20 - Prob. 46PPCh. 20 - Prob. 47PPCh. 20 - Prob. 48PPCh. 20 - Prob. 49PPCh. 20 - Prob. 50PPCh. 20 - Prob. 51PPCh. 20 - Prob. 52PPCh. 20 - Prob. 53PPCh. 20 - Prob. 54PPCh. 20 - Prob. 55PPCh. 20 - Prob. 56PPCh. 20 - Prob. 57PPCh. 20 - Prob. 58PPCh. 20 - Prob. 59PPCh. 20 - Prob. 60PPCh. 20 - Prob. 61PPCh. 20 - Prob. 62PPCh. 20 - Prob. 63PPCh. 20 - Prob. 64PPCh. 20 - Prob. 65PPCh. 20 - Prob. 66PPCh. 20 - Prob. 67PPCh. 20 - Prob. 68PPCh. 20 - Prob. 69PPCh. 20 - Prob. 70PPCh. 20 - Prob. 71PPCh. 20 - Prob. 72PPCh. 20 - Prob. 73PPCh. 20 - Prob. 74PPCh. 20 - Prob. 75PPCh. 20 - Prob. 76IPCh. 20 - Prob. 77IPCh. 20 - Prob. 78IPCh. 20 - Prob. 79IPCh. 20 - Prob. 80IPCh. 20 - Prob. 81IPCh. 20 - Prob. 82IPCh. 20 - Prob. 83IPCh. 20 - Prob. 84IPCh. 20 - Prob. 85IPCh. 20 - Prob. 86IP
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