Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 20.1, Problem 20.1PSP
Use partial atomic orbital box diagrams to explain the number of unpaired electrons shown in Figure 20.2 for (a) Mn2+ and (b) Cr3+.
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Write the condensed ground-state electron configurations of these transition metal ions, and indicate which are paramagnetic. (Type your answer using the format [Ar] 4s2 3d10 4p1 for [Ar] 4s23d104p1.)
(a) Mo3+
O paramagnetic
O diamagnetic
(b) Hf2+
O paramagnetic
O diamagnetic
(c) Mn2+
O paramagnetic
O diamagnetic
(d) v3+
O paramagnetic
O diamagnetic
Are compounds of these ground-state ions paramagnetic?(a) Ti²⁺(b) Zn²⁺(c) Ca²⁺(d) Sn²⁺
(c) Give the ground-state electron configuration for each of following substances:
(1) Phosphorus
(ii) Cr(II) ion
(iii) Sulfide ion
(iv) Ti(IV) ion
Chapter 20 Solutions
Chemistry: The Molecular Science
Ch. 20.1 - Use partial atomic orbital box diagrams to explain...Ch. 20.1 - Prob. 20.1ECh. 20.1 - Prob. 20.2ECh. 20.2 - Prob. 20.2PSPCh. 20.2 - Prob. 20.3PSPCh. 20.2 - Prob. 20.3ECh. 20.3 - Explain how zinc and lead could be separated from...Ch. 20.3 - Prob. 20.4ECh. 20.4 - Prob. 20.5ECh. 20.5 - Use data from Appendix J to calculate the enthalpy...
Ch. 20.5 - Use Le Chatelier’s principle to explain how the...Ch. 20.5 - At what pH does Ecell = 0.00 V for the reduction...Ch. 20.6 - Prob. 20.6PSPCh. 20.6 - Prob. 20.8CECh. 20.6 - (a) Name this coordination compound:...Ch. 20.6 - Prob. 20.9CECh. 20.6 - Prob. 20.8PSPCh. 20.6 - Prob. 20.10CECh. 20.6 - Prob. 20.11CECh. 20.6 - Prob. 20.9PSPCh. 20.6 - Prob. 20.12ECh. 20.7 - Prob. 20.10PSPCh. 20.7 - Prob. 20.13CECh. 20.7 - Prob. 20.14CECh. 20 - Prob. 1QRTCh. 20 - Prob. 2QRTCh. 20 - Prob. 3QRTCh. 20 - Prob. 4QRTCh. 20 - Prob. 5QRTCh. 20 - Prob. 6QRTCh. 20 - Prob. 7QRTCh. 20 - Prob. 8QRTCh. 20 - Prob. 9QRTCh. 20 - Prob. 10QRTCh. 20 - Prob. 11QRTCh. 20 - Prob. 12QRTCh. 20 - Prob. 13QRTCh. 20 - Prob. 14QRTCh. 20 - Prob. 15QRTCh. 20 - Which Period 4 transition-metal ions are...Ch. 20 - Prob. 17QRTCh. 20 - Prob. 18QRTCh. 20 - Prob. 19QRTCh. 20 - Prob. 20QRTCh. 20 - Prob. 21QRTCh. 20 - Prob. 22QRTCh. 20 - Prob. 23QRTCh. 20 - Prob. 24QRTCh. 20 - Prob. 25QRTCh. 20 - Prob. 26QRTCh. 20 - Prob. 27QRTCh. 20 - Prob. 28QRTCh. 20 - Prob. 29QRTCh. 20 - Prob. 30QRTCh. 20 - Prob. 31QRTCh. 20 - Prob. 32QRTCh. 20 - Prob. 33QRTCh. 20 - Prob. 34QRTCh. 20 - Prob. 35QRTCh. 20 - Prob. 36QRTCh. 20 - Prob. 37QRTCh. 20 - Prob. 38QRTCh. 20 - Prob. 39QRTCh. 20 - Prob. 40QRTCh. 20 - Prob. 41QRTCh. 20 - Prob. 42QRTCh. 20 - Prob. 43QRTCh. 20 - Prob. 44QRTCh. 20 - Prob. 45QRTCh. 20 - Prob. 46QRTCh. 20 - Prob. 47QRTCh. 20 - Prob. 48QRTCh. 20 - Prob. 49QRTCh. 20 - Prob. 50QRTCh. 20 - Prob. 51QRTCh. 20 - Prob. 52QRTCh. 20 - Give the charge on the central metal ion in each...Ch. 20 - Prob. 54QRTCh. 20 - Prob. 55QRTCh. 20 - Classify each ligand as monodentate, bidentate,...Ch. 20 - Prob. 57QRTCh. 20 - Prob. 58QRTCh. 20 - Prob. 59QRTCh. 20 - Prob. 60QRTCh. 20 - Prob. 61QRTCh. 20 - Prob. 62QRTCh. 20 - Prob. 63QRTCh. 20 - Prob. 64QRTCh. 20 - Prob. 65QRTCh. 20 - Prob. 66QRTCh. 20 - Prob. 67QRTCh. 20 - Prob. 68QRTCh. 20 - Prob. 69QRTCh. 20 - Prob. 70QRTCh. 20 - Prob. 71QRTCh. 20 - Prob. 72QRTCh. 20 - Prob. 73QRTCh. 20 - Prob. 74QRTCh. 20 - How many unpaired electrons are in the high-spin...Ch. 20 - Prob. 76QRTCh. 20 - Prob. 77QRTCh. 20 - Prob. 78QRTCh. 20 - An aqueous solution of [Rh(C2O4)3]3− is yellow....Ch. 20 - Prob. 80QRTCh. 20 - Prob. 81QRTCh. 20 - Prob. 82QRTCh. 20 - Prob. 83QRTCh. 20 - Prob. 84QRTCh. 20 - Give the electron configuration of (a) Ti3+. (b)...Ch. 20 - Prob. 86QRTCh. 20 - Prob. 87QRTCh. 20 - Prob. 88QRTCh. 20 - Prob. 89QRTCh. 20 - Prob. 90QRTCh. 20 - Prob. 91QRTCh. 20 - Prob. 92QRTCh. 20 - Prob. 93QRTCh. 20 - Prob. 94QRTCh. 20 - Prob. 95QRTCh. 20 - Prob. 96QRTCh. 20 - Prob. 97QRTCh. 20 - Prob. 98QRTCh. 20 - Prob. 99QRTCh. 20 - Prob. 100QRTCh. 20 - Prob. 101QRTCh. 20 - Prob. 103QRTCh. 20 - Prob. 104QRTCh. 20 - Prob. 105QRTCh. 20 - Prob. 106QRTCh. 20 -
Repeat the directions for Question 106 using a...Ch. 20 - Prob. 113QRTCh. 20 - Prob. 114QRTCh. 20 - Prob. 115QRTCh. 20 - Prob. 116QRTCh. 20 - Prob. 117QRTCh. 20 - Prob. 118QRTCh. 20 - Prob. 119QRTCh. 20 - Prob. 120QRTCh. 20 - The glycinate ion (gly) is H2NCH2CO2. It can act...Ch. 20 - Five-coordinate coordination complexes are known,...Ch. 20 - Prob. 123QRTCh. 20 - Prob. 124QRTCh. 20 - Two different compounds are known with the formula...Ch. 20 - Prob. 126QRT
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- (c) Give the ground-state electron configuration for each of following substances: (i) Phosphorus (ii) Cr(II) ion (iii) Sulfide ion (iv)Ti(IV) ionarrow_forward(a) Write the electronic configuration of Cu2+ (Atomic No of Cu=29) (b) Explain Cr has the configurations (Ar) 4s1 3d5 rather than (Ar) 4s2 3d4 (C)HF has 19°C whereas H2O has a of 100°Carrow_forwardShow that Cr(CO)6 obeys the 18-electron rule.arrow_forward
- Write out the ground-state electron configurations of(a) Ti3+, (b) Ru2+, (c) Au3+, (d) Mn4+.arrow_forwarda) How many core electrons does the Ni atom have? b) How many valence electrons are in the Ni3+ ion? Which transition-metal ion with a 3+ charge has the electron configuration [Kr]4d5 ?arrow_forwardOn the basis of the 18-electron rule: a) Determine the identity of the metal M in [M(CO)7]+ b) Determine the charge Z on [Co(CO)3]Zarrow_forward
- It has been observed that first ionization energy of 5 d series of transition elements are higher than that of 3d and 4d series, explain why?arrow_forwardWrite down the set of quantum numbers that describe the 4th and 11th electrons of Mg atom. 2. А. В. Write down the orbital diagram for each transition metal ion below, and predict whether the ion is paramagnetic or diamagnetic. (a) Cul* (Z=29) (b) Zn²* (Z=30) С. Are the following combinations allowed? If not, show two ways to correct them: (a) n = 2; 1 = 0; mị = -1; ms= +1/2 (b) n = 3; 1= 1; mị = 0, mş=-1/2 (c) n= 4; 1= 3; mị = -1; ms= -1/2 (d) n = 3; 1= 3; mị = +2; mş=+1/2 In which of the following ground state electron distribution, the Hund's rule is violated? Justify your answer. D. (A) (B) (C) (D) Е. Which of the following is a violation of Pauli's exclusion principle? Justify your answer. (A) 11 (B) tt (C) 14 (D) farrow_forwardWhat element has the abbreviated electron configuration of [Kr]5s24d2?arrow_forward
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