Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 20, Problem 56QRT
Classify each ligand as monodentate, bidentate, and so on.
- (a) (CH3)3P
- (b) H2N─(CH2)2─NH─(CH2)2─NH2
- (c) H2O
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Pyridine (CsHgN), abbreviated py, is the molecule
N:
(a) Would you expect pyridine to act as a monodentate or
bidentate ligand? (b) For the equilibrium reaction
[Ru(py),(bipy)]²+ + 2 py
= [Ru(py),J* + bipy
would you predict the equilibrium constant to be larger or
smaller than one?
Draw orbital-energy splitting diagrams and use the spec-trochemical series to show the orbital occupancy for each of thefollowing (assuming that H₂O is a weak-field ligand):(a) [MoCl₆]³⁻(b) [Ni(H₂O)₆]²⁺(c) [Ni(CN)₄]²⁻
Assign reason for each of the following :(i) Transition elements exhibit paramagnetic behaviour.(ii) Co2+. is easily oxidised in the presence of a strong ligand.
Chapter 20 Solutions
Chemistry: The Molecular Science
Ch. 20.1 - Use partial atomic orbital box diagrams to explain...Ch. 20.1 - Prob. 20.1ECh. 20.1 - Prob. 20.2ECh. 20.2 - Prob. 20.2PSPCh. 20.2 - Prob. 20.3PSPCh. 20.2 - Prob. 20.3ECh. 20.3 - Explain how zinc and lead could be separated from...Ch. 20.3 - Prob. 20.4ECh. 20.4 - Prob. 20.5ECh. 20.5 - Use data from Appendix J to calculate the enthalpy...
Ch. 20.5 - Use Le Chatelier’s principle to explain how the...Ch. 20.5 - At what pH does Ecell = 0.00 V for the reduction...Ch. 20.6 - Prob. 20.6PSPCh. 20.6 - Prob. 20.8CECh. 20.6 - (a) Name this coordination compound:...Ch. 20.6 - Prob. 20.9CECh. 20.6 - Prob. 20.8PSPCh. 20.6 - Prob. 20.10CECh. 20.6 - Prob. 20.11CECh. 20.6 - Prob. 20.9PSPCh. 20.6 - Prob. 20.12ECh. 20.7 - Prob. 20.10PSPCh. 20.7 - Prob. 20.13CECh. 20.7 - Prob. 20.14CECh. 20 - Prob. 1QRTCh. 20 - Prob. 2QRTCh. 20 - Prob. 3QRTCh. 20 - Prob. 4QRTCh. 20 - Prob. 5QRTCh. 20 - Prob. 6QRTCh. 20 - Prob. 7QRTCh. 20 - Prob. 8QRTCh. 20 - Prob. 9QRTCh. 20 - Prob. 10QRTCh. 20 - Prob. 11QRTCh. 20 - Prob. 12QRTCh. 20 - Prob. 13QRTCh. 20 - Prob. 14QRTCh. 20 - Prob. 15QRTCh. 20 - Which Period 4 transition-metal ions are...Ch. 20 - Prob. 17QRTCh. 20 - Prob. 18QRTCh. 20 - Prob. 19QRTCh. 20 - Prob. 20QRTCh. 20 - Prob. 21QRTCh. 20 - Prob. 22QRTCh. 20 - Prob. 23QRTCh. 20 - Prob. 24QRTCh. 20 - Prob. 25QRTCh. 20 - Prob. 26QRTCh. 20 - Prob. 27QRTCh. 20 - Prob. 28QRTCh. 20 - Prob. 29QRTCh. 20 - Prob. 30QRTCh. 20 - Prob. 31QRTCh. 20 - Prob. 32QRTCh. 20 - Prob. 33QRTCh. 20 - Prob. 34QRTCh. 20 - Prob. 35QRTCh. 20 - Prob. 36QRTCh. 20 - Prob. 37QRTCh. 20 - Prob. 38QRTCh. 20 - Prob. 39QRTCh. 20 - Prob. 40QRTCh. 20 - Prob. 41QRTCh. 20 - Prob. 42QRTCh. 20 - Prob. 43QRTCh. 20 - Prob. 44QRTCh. 20 - Prob. 45QRTCh. 20 - Prob. 46QRTCh. 20 - Prob. 47QRTCh. 20 - Prob. 48QRTCh. 20 - Prob. 49QRTCh. 20 - Prob. 50QRTCh. 20 - Prob. 51QRTCh. 20 - Prob. 52QRTCh. 20 - Give the charge on the central metal ion in each...Ch. 20 - Prob. 54QRTCh. 20 - Prob. 55QRTCh. 20 - Classify each ligand as monodentate, bidentate,...Ch. 20 - Prob. 57QRTCh. 20 - Prob. 58QRTCh. 20 - Prob. 59QRTCh. 20 - Prob. 60QRTCh. 20 - Prob. 61QRTCh. 20 - Prob. 62QRTCh. 20 - Prob. 63QRTCh. 20 - Prob. 64QRTCh. 20 - Prob. 65QRTCh. 20 - Prob. 66QRTCh. 20 - Prob. 67QRTCh. 20 - Prob. 68QRTCh. 20 - Prob. 69QRTCh. 20 - Prob. 70QRTCh. 20 - Prob. 71QRTCh. 20 - Prob. 72QRTCh. 20 - Prob. 73QRTCh. 20 - Prob. 74QRTCh. 20 - How many unpaired electrons are in the high-spin...Ch. 20 - Prob. 76QRTCh. 20 - Prob. 77QRTCh. 20 - Prob. 78QRTCh. 20 - An aqueous solution of [Rh(C2O4)3]3− is yellow....Ch. 20 - Prob. 80QRTCh. 20 - Prob. 81QRTCh. 20 - Prob. 82QRTCh. 20 - Prob. 83QRTCh. 20 - Prob. 84QRTCh. 20 - Give the electron configuration of (a) Ti3+. (b)...Ch. 20 - Prob. 86QRTCh. 20 - Prob. 87QRTCh. 20 - Prob. 88QRTCh. 20 - Prob. 89QRTCh. 20 - Prob. 90QRTCh. 20 - Prob. 91QRTCh. 20 - Prob. 92QRTCh. 20 - Prob. 93QRTCh. 20 - Prob. 94QRTCh. 20 - Prob. 95QRTCh. 20 - Prob. 96QRTCh. 20 - Prob. 97QRTCh. 20 - Prob. 98QRTCh. 20 - Prob. 99QRTCh. 20 - Prob. 100QRTCh. 20 - Prob. 101QRTCh. 20 - Prob. 103QRTCh. 20 - Prob. 104QRTCh. 20 - Prob. 105QRTCh. 20 - Prob. 106QRTCh. 20 -
Repeat the directions for Question 106 using a...Ch. 20 - Prob. 113QRTCh. 20 - Prob. 114QRTCh. 20 - Prob. 115QRTCh. 20 - Prob. 116QRTCh. 20 - Prob. 117QRTCh. 20 - Prob. 118QRTCh. 20 - Prob. 119QRTCh. 20 - Prob. 120QRTCh. 20 - The glycinate ion (gly) is H2NCH2CO2. It can act...Ch. 20 - Five-coordinate coordination complexes are known,...Ch. 20 - Prob. 123QRTCh. 20 - Prob. 124QRTCh. 20 - Two different compounds are known with the formula...Ch. 20 - Prob. 126QRT
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Give the number of unpaired electrons in octahedral complexes with strong-field ligands for (a) Rh3+ (b) Mn3+ (c) Ag+ (d) Pt4+ (e) Au3+arrow_forwardFour different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forward
- Trimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(Il) chloride in acetone, a blue compound that has a molecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?arrow_forwardOne of the following nitrogen compounds or ions is not capable of serving as a ligand: NH4+, NH3, NH2. Identify this species, and explain your answer.arrow_forwardPredict whether the carbonate ligand CO32- will coordinate to a metal center as a monodentate, bidentate, or tridentate ligand.arrow_forward
- For each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8arrow_forwardWhich of the following ligands is expected to be monodentate, and which might be polydentate? (a) CH3NH2 (b) CH3CN (c) N3 (d) en (e) Br (f) phenarrow_forwardAn aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forward
- The square-planar complex Pt(en)Cl2 has chloride ligands in a cis configuration. No trans isomer is known. Based on the bond lengths and bond angles of carbon and nitrogen in the ethylenediamine ligand, explain why the trans compound is not possible.arrow_forward(b) Consider the oxalate (ox) ligand and answer the following questions:(i) Draw the structure of the ox ligand.(ii) Identify all the donor atoms of the ligand.(iii) What is the denticity of the ligand?(iv) What is the charge of the ligand?(v) Draw the structure of a homoleptic octahedral complex with ox as the ligand.Clearly show the geometry at the metal centre.(vi) Identify the stereoisomer in the structure drawn.arrow_forwardThe octahedral complex ion [CoF6]3– is paramagnetic with four unpaired 3d-electrons, whereas the complex ion [Co(CN)6]3– is diamagnetic. (a) Draw the crystal-field energy diagram for 3d-electrons in each complex. (b) Which ligand causes a larger splitting of d-orbitals in Co3+? (c) Which complex ion exhibits absorption spectrum with the longer max? Explain.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
The Bohr Model of the atom and Atomic Emission Spectra: Atomic Structure tutorial | Crash Chemistry; Author: Crash Chemistry Academy;https://www.youtube.com/watch?v=apuWi_Fbtys;License: Standard YouTube License, CC-BY