Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 20, Problem 65QRT
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[Co(H2O)6]2+ (aq) + 4 Cl-(aq )⇆ [CoCl4]2-(aq) + 6 H2O
3. Does the value of the equilibrium constant (K) for this reaction increase, decrease, or
remain the same as the concentration of chloride increases? Explain your answer
incorporating the definition of an equilibrium constant.
For [Co(NH3)6]3+ , Kf has a value of 5.00 × 1031. Calculate the concentration of free, uncomplexed Co3+ ions in a solution that contains a total of 0.160 mol/L cobalt III ions and an equilibrium concentration of 0.50 M NH3.
(a) Draw a Lewis dot and cross structure (including any lone pairs) for a NBr3
molecule and determine the shape of the molecule and number of valence
electrons.
(b)
Six ammonia ligands form a complex ion with Co²+.
What is the overall charge of the complex ion?
Write the formula for the complex ion.
What is the coordination number of the complex ion?
Explain how ammonia ligands form a complex ion with Co²+?
What is the geometry of the complex ion?
Would you expect the complex to be coloured? Explain why?
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ii.
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Chapter 20 Solutions
Chemistry: The Molecular Science
Ch. 20.1 - Use partial atomic orbital box diagrams to explain...Ch. 20.1 - Prob. 20.1ECh. 20.1 - Prob. 20.2ECh. 20.2 - Prob. 20.2PSPCh. 20.2 - Prob. 20.3PSPCh. 20.2 - Prob. 20.3ECh. 20.3 - Explain how zinc and lead could be separated from...Ch. 20.3 - Prob. 20.4ECh. 20.4 - Prob. 20.5ECh. 20.5 - Use data from Appendix J to calculate the enthalpy...
Ch. 20.5 - Use Le Chatelier’s principle to explain how the...Ch. 20.5 - At what pH does Ecell = 0.00 V for the reduction...Ch. 20.6 - Prob. 20.6PSPCh. 20.6 - Prob. 20.8CECh. 20.6 - (a) Name this coordination compound:...Ch. 20.6 - Prob. 20.9CECh. 20.6 - Prob. 20.8PSPCh. 20.6 - Prob. 20.10CECh. 20.6 - Prob. 20.11CECh. 20.6 - Prob. 20.9PSPCh. 20.6 - Prob. 20.12ECh. 20.7 - Prob. 20.10PSPCh. 20.7 - Prob. 20.13CECh. 20.7 - Prob. 20.14CECh. 20 - Prob. 1QRTCh. 20 - Prob. 2QRTCh. 20 - Prob. 3QRTCh. 20 - Prob. 4QRTCh. 20 - Prob. 5QRTCh. 20 - Prob. 6QRTCh. 20 - Prob. 7QRTCh. 20 - Prob. 8QRTCh. 20 - Prob. 9QRTCh. 20 - Prob. 10QRTCh. 20 - Prob. 11QRTCh. 20 - Prob. 12QRTCh. 20 - Prob. 13QRTCh. 20 - Prob. 14QRTCh. 20 - Prob. 15QRTCh. 20 - Which Period 4 transition-metal ions are...Ch. 20 - Prob. 17QRTCh. 20 - Prob. 18QRTCh. 20 - Prob. 19QRTCh. 20 - Prob. 20QRTCh. 20 - Prob. 21QRTCh. 20 - Prob. 22QRTCh. 20 - Prob. 23QRTCh. 20 - Prob. 24QRTCh. 20 - Prob. 25QRTCh. 20 - Prob. 26QRTCh. 20 - Prob. 27QRTCh. 20 - Prob. 28QRTCh. 20 - Prob. 29QRTCh. 20 - Prob. 30QRTCh. 20 - Prob. 31QRTCh. 20 - Prob. 32QRTCh. 20 - Prob. 33QRTCh. 20 - Prob. 34QRTCh. 20 - Prob. 35QRTCh. 20 - Prob. 36QRTCh. 20 - Prob. 37QRTCh. 20 - Prob. 38QRTCh. 20 - Prob. 39QRTCh. 20 - Prob. 40QRTCh. 20 - Prob. 41QRTCh. 20 - Prob. 42QRTCh. 20 - Prob. 43QRTCh. 20 - Prob. 44QRTCh. 20 - Prob. 45QRTCh. 20 - Prob. 46QRTCh. 20 - Prob. 47QRTCh. 20 - Prob. 48QRTCh. 20 - Prob. 49QRTCh. 20 - Prob. 50QRTCh. 20 - Prob. 51QRTCh. 20 - Prob. 52QRTCh. 20 - Give the charge on the central metal ion in each...Ch. 20 - Prob. 54QRTCh. 20 - Prob. 55QRTCh. 20 - Classify each ligand as monodentate, bidentate,...Ch. 20 - Prob. 57QRTCh. 20 - Prob. 58QRTCh. 20 - Prob. 59QRTCh. 20 - Prob. 60QRTCh. 20 - Prob. 61QRTCh. 20 - Prob. 62QRTCh. 20 - Prob. 63QRTCh. 20 - Prob. 64QRTCh. 20 - Prob. 65QRTCh. 20 - Prob. 66QRTCh. 20 - Prob. 67QRTCh. 20 - Prob. 68QRTCh. 20 - Prob. 69QRTCh. 20 - Prob. 70QRTCh. 20 - Prob. 71QRTCh. 20 - Prob. 72QRTCh. 20 - Prob. 73QRTCh. 20 - Prob. 74QRTCh. 20 - How many unpaired electrons are in the high-spin...Ch. 20 - Prob. 76QRTCh. 20 - Prob. 77QRTCh. 20 - Prob. 78QRTCh. 20 - An aqueous solution of [Rh(C2O4)3]3− is yellow....Ch. 20 - Prob. 80QRTCh. 20 - Prob. 81QRTCh. 20 - Prob. 82QRTCh. 20 - Prob. 83QRTCh. 20 - Prob. 84QRTCh. 20 - Give the electron configuration of (a) Ti3+. (b)...Ch. 20 - Prob. 86QRTCh. 20 - Prob. 87QRTCh. 20 - Prob. 88QRTCh. 20 - Prob. 89QRTCh. 20 - Prob. 90QRTCh. 20 - Prob. 91QRTCh. 20 - Prob. 92QRTCh. 20 - Prob. 93QRTCh. 20 - Prob. 94QRTCh. 20 - Prob. 95QRTCh. 20 - Prob. 96QRTCh. 20 - Prob. 97QRTCh. 20 - Prob. 98QRTCh. 20 - Prob. 99QRTCh. 20 - Prob. 100QRTCh. 20 - Prob. 101QRTCh. 20 - Prob. 103QRTCh. 20 - Prob. 104QRTCh. 20 - Prob. 105QRTCh. 20 - Prob. 106QRTCh. 20 -
Repeat the directions for Question 106 using a...Ch. 20 - Prob. 113QRTCh. 20 - Prob. 114QRTCh. 20 - Prob. 115QRTCh. 20 - Prob. 116QRTCh. 20 - Prob. 117QRTCh. 20 - Prob. 118QRTCh. 20 - Prob. 119QRTCh. 20 - Prob. 120QRTCh. 20 - The glycinate ion (gly) is H2NCH2CO2. It can act...Ch. 20 - Five-coordinate coordination complexes are known,...Ch. 20 - Prob. 123QRTCh. 20 - Prob. 124QRTCh. 20 - Two different compounds are known with the formula...Ch. 20 - Prob. 126QRT
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- what is the shape of [Co(NH3)6]^3+ ?arrow_forwardExplain how the diphosphate ion, [O3P−O−PO3]4−, can function as a water softener that prevents the precipitation of Fe2+ as an insoluble iron salt.arrow_forwardFor each of the following reactions, identify the acid and the base. Also indicate which acid-base definition is most applicable. Fe3+ + 6 SCN– →[Fe(SCN)6]3– HClO4 + (CH3)3N → (CH3)3NH+ + ClO4– [Co(H2O)6]2+ + 4 HCl → [CoCl4]2– + 4 H3O+ + 2 H2Oarrow_forward
- How many geometric isomers exist for [CoCl2(en)2]Cl? How could you determine if your product contains a single geometric isomer or a mixture of geometric isomers?arrow_forwardDraw and give the shape of the complex ion belowarrow_forwardConsider the following tetrahedral complex ions: [Zr(H₂O)4]²+, [Zr(CN)4]²¯, and [Zr(OH)4]². Arrange these in terms of increasing wavelength of the color they appear. [Zr(OH)4]²- < [Zr(CN)4]² < [Zr(H₂O)4]²+ O [Zr(CN)4]²- < [Zr(OH)4]²¯ < [Zr(H₂O)4]²+ [Zr(CN)4]² < [Zr(H₂O)4]²+ < [Zr(OH)4]²- O [Zr(H₂O)4]²+ < [Zr(CN)4]²¯ < [Zr(OH)4]²- [Zr(OH)4]² < [Zr(H₂O)4]²+ < [Zr(CN)4]²-arrow_forward
- what is the reaction in FeCl3 + pb(no3)2arrow_forwardIn the presence of aqueous ammonia, cobalt(III) forms the complex ion Co(NH3)63+. Determine the molar concentration of free cobalt(III) ion in solution when 0.210 mole of Co(NO3)3 is dissolved in a liter of 2.50 M aqueous ammonia.arrow_forwardExplain why the species Fe(H2O)6 2+ is a complex ion.arrow_forward
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