
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Question
Chapter 20, Problem 39QRT
Interpretation Introduction
Interpretation:
Reason for adding other metals to silver and gold has to be described.
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
Check
Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 20 Solutions
Chemistry: The Molecular Science
Ch. 20.1 - Use partial atomic orbital box diagrams to explain...Ch. 20.1 - Prob. 20.1ECh. 20.1 - Prob. 20.2ECh. 20.2 - Prob. 20.2PSPCh. 20.2 - Prob. 20.3PSPCh. 20.2 - Prob. 20.3ECh. 20.3 - Explain how zinc and lead could be separated from...Ch. 20.3 - Prob. 20.4ECh. 20.4 - Prob. 20.5ECh. 20.5 - Use data from Appendix J to calculate the enthalpy...
Ch. 20.5 - Use Le Chatelier’s principle to explain how the...Ch. 20.5 - At what pH does Ecell = 0.00 V for the reduction...Ch. 20.6 - Prob. 20.6PSPCh. 20.6 - Prob. 20.8CECh. 20.6 - (a) Name this coordination compound:...Ch. 20.6 - Prob. 20.9CECh. 20.6 - Prob. 20.8PSPCh. 20.6 - Prob. 20.10CECh. 20.6 - Prob. 20.11CECh. 20.6 - Prob. 20.9PSPCh. 20.6 - Prob. 20.12ECh. 20.7 - Prob. 20.10PSPCh. 20.7 - Prob. 20.13CECh. 20.7 - Prob. 20.14CECh. 20 - Prob. 1QRTCh. 20 - Prob. 2QRTCh. 20 - Prob. 3QRTCh. 20 - Prob. 4QRTCh. 20 - Prob. 5QRTCh. 20 - Prob. 6QRTCh. 20 - Prob. 7QRTCh. 20 - Prob. 8QRTCh. 20 - Prob. 9QRTCh. 20 - Prob. 10QRTCh. 20 - Prob. 11QRTCh. 20 - Prob. 12QRTCh. 20 - Prob. 13QRTCh. 20 - Prob. 14QRTCh. 20 - Prob. 15QRTCh. 20 - Which Period 4 transition-metal ions are...Ch. 20 - Prob. 17QRTCh. 20 - Prob. 18QRTCh. 20 - Prob. 19QRTCh. 20 - Prob. 20QRTCh. 20 - Prob. 21QRTCh. 20 - Prob. 22QRTCh. 20 - Prob. 23QRTCh. 20 - Prob. 24QRTCh. 20 - Prob. 25QRTCh. 20 - Prob. 26QRTCh. 20 - Prob. 27QRTCh. 20 - Prob. 28QRTCh. 20 - Prob. 29QRTCh. 20 - Prob. 30QRTCh. 20 - Prob. 31QRTCh. 20 - Prob. 32QRTCh. 20 - Prob. 33QRTCh. 20 - Prob. 34QRTCh. 20 - Prob. 35QRTCh. 20 - Prob. 36QRTCh. 20 - Prob. 37QRTCh. 20 - Prob. 38QRTCh. 20 - Prob. 39QRTCh. 20 - Prob. 40QRTCh. 20 - Prob. 41QRTCh. 20 - Prob. 42QRTCh. 20 - Prob. 43QRTCh. 20 - Prob. 44QRTCh. 20 - Prob. 45QRTCh. 20 - Prob. 46QRTCh. 20 - Prob. 47QRTCh. 20 - Prob. 48QRTCh. 20 - Prob. 49QRTCh. 20 - Prob. 50QRTCh. 20 - Prob. 51QRTCh. 20 - Prob. 52QRTCh. 20 - Give the charge on the central metal ion in each...Ch. 20 - Prob. 54QRTCh. 20 - Prob. 55QRTCh. 20 - Classify each ligand as monodentate, bidentate,...Ch. 20 - Prob. 57QRTCh. 20 - Prob. 58QRTCh. 20 - Prob. 59QRTCh. 20 - Prob. 60QRTCh. 20 - Prob. 61QRTCh. 20 - Prob. 62QRTCh. 20 - Prob. 63QRTCh. 20 - Prob. 64QRTCh. 20 - Prob. 65QRTCh. 20 - Prob. 66QRTCh. 20 - Prob. 67QRTCh. 20 - Prob. 68QRTCh. 20 - Prob. 69QRTCh. 20 - Prob. 70QRTCh. 20 - Prob. 71QRTCh. 20 - Prob. 72QRTCh. 20 - Prob. 73QRTCh. 20 - Prob. 74QRTCh. 20 - How many unpaired electrons are in the high-spin...Ch. 20 - Prob. 76QRTCh. 20 - Prob. 77QRTCh. 20 - Prob. 78QRTCh. 20 - An aqueous solution of [Rh(C2O4)3]3− is yellow....Ch. 20 - Prob. 80QRTCh. 20 - Prob. 81QRTCh. 20 - Prob. 82QRTCh. 20 - Prob. 83QRTCh. 20 - Prob. 84QRTCh. 20 - Give the electron configuration of (a) Ti3+. (b)...Ch. 20 - Prob. 86QRTCh. 20 - Prob. 87QRTCh. 20 - Prob. 88QRTCh. 20 - Prob. 89QRTCh. 20 - Prob. 90QRTCh. 20 - Prob. 91QRTCh. 20 - Prob. 92QRTCh. 20 - Prob. 93QRTCh. 20 - Prob. 94QRTCh. 20 - Prob. 95QRTCh. 20 - Prob. 96QRTCh. 20 - Prob. 97QRTCh. 20 - Prob. 98QRTCh. 20 - Prob. 99QRTCh. 20 - Prob. 100QRTCh. 20 - Prob. 101QRTCh. 20 - Prob. 103QRTCh. 20 - Prob. 104QRTCh. 20 - Prob. 105QRTCh. 20 - Prob. 106QRTCh. 20 -
Repeat the directions for Question 106 using a...Ch. 20 - Prob. 113QRTCh. 20 - Prob. 114QRTCh. 20 - Prob. 115QRTCh. 20 - Prob. 116QRTCh. 20 - Prob. 117QRTCh. 20 - Prob. 118QRTCh. 20 - Prob. 119QRTCh. 20 - Prob. 120QRTCh. 20 - The glycinate ion (gly) is H2NCH2CO2. It can act...Ch. 20 - Five-coordinate coordination complexes are known,...Ch. 20 - Prob. 123QRTCh. 20 - Prob. 124QRTCh. 20 - Two different compounds are known with the formula...Ch. 20 - Prob. 126QRT
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- calculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forwardtrue or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forward
- true or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forwardtrue or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forward
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