ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
bartleby

Concept explainers

bartleby

Videos

Question
Book Icon
Chapter 20, Problem 59P
Interpretation Introduction

Interpretation:

The structures of two five-membered-ring lactones are to be drawn.

Concept Introduction:

The aldaric acid of D-glucose forms two five membered-ring lactones.

Aldaric acid, also known as saccharic acid is a poly hydroxy dicarboxylic acid that is formally produced by the oxidation of aldose at both terminals.  Aldaric acids are synthesized by the process of oxidation of aldose with nitric acid. These are also called sugar acids.

In these acids terminal hydroxyl and carbonyl groups of the sugars have been replaced by terminal carboxylic acids and are characterized by the formula COOH(CHOH)nCOOH.  Here, n is the number of carbon units present in the chain other than terminal carbons.

Lactones are cyclic compounds. These are formed by intramolecular esterification of the corresponding Saccharide units.

Blurred answer
Students have asked these similar questions
Drawing Arrows 1 I I 1 heat 1 51 MO + Drag To Und Settings Done 0 0 Jan 31 3:5
Don't used hand raiting
Gramicidin A can adopt more than one structure; NMR spectroscopy has revealed an “end-to-end” dimer form, and x-ray crystallography has revealed an “anti-parallel double- helical” form. Briefly outline and describe an experimentalapproach/strategy to investigate WHICH configuration (“end-to-end dimer” vs “anti-paralleldouble helical”) gramicidin adopts in an actual lipid bilayer.

Chapter 20 Solutions

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL

Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Text book image
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
Text book image
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Cengage Learning
Lipids - Fatty Acids, Triglycerides, Phospholipids, Terpenes, Waxes, Eicosanoids; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=7dmoH5dAvpY;License: Standard YouTube License, CC-BY