ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
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Chapter 20.3, Problem 5P

a)

Interpretation Introduction

Interpretation:

A sugar that is C3 epimer of D-xylose is to be stated.

Concept Introduction:

Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers.  For example,D-xylose and D-ribose are the C3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

b)

Interpretation Introduction

Interpretation:

A sugar that is C5 epimer of D-allose is to be stated.

Concept Introduction:

Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example, D-xylose and D-ribose are the C3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

c)

Interpretation Introduction

Interpretation:

A sugar that is C4 epimer of L-gulose is to be stated.

Concept Introduction:

Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example, D-xylose and D-ribose are the C3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

d)

Interpretation Introduction

Interpretation:

A sugar that is C4 epimer of D-lyxose is to be stated.

Concept Introduction:

Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example, D-xylose and D-ribose are the C3 epimers because they differ in the configuration only at carbon number 3 starting from the above rest whole structure is same.

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A buffered solution containing dissolved aniline, CH,NH2, and aniline hydrochloride, CH, NH, Cl, has a pH of 5.41. Determine the concentration of CH, NH in the solution if the concentration of CH, NH, is 0.305 M. The pK of aniline is 9.13. [CHẠNH] = Calculate the change in pH of the solution, ApH, if 0.375 g NaOH is added to the buffer for a final volume of 1.40 L. Assume that any contribution of NaOH to the volume is negligible. ApH = M
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Chapter 20 Solutions

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL

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