ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
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Chapter 20.4, Problem 8P

a)

Interpretation Introduction

Interpretation:

The number of stereoisomers that are possible for ketoheptose is to be stated.

Concept Introduction:

Stereoisomers are the isomers having same molecular formula but they differ in the arrangement of molecules in space.  Enantiomers are the molecules that are non-superimposable on one another.

The number of possible stereoisomers is calculated as 2n where n is the number of asymmetric carbons present in a compound.

b)

Interpretation Introduction

Interpretation:

The number of stereoisomers that are possible for aldoheptose is to be stated.

Concept Introduction:

Stereoisomers are the isomers having same molecular formula but they differ from the arrangement of molecules in the space.  Enantiomers are the molecules that are non-superimposable on one another.

The number of possible stereoisomers is calculated as 2n where n is the number of asymmetric carbons present in a compound.

c)

Interpretation Introduction

Interpretation:

The number of stereoisomers that are possible for a ketotriose is to be stated.

Concept Introduction:

Stereoisomers are the isomers having same molecular formula but they differ from the arrangement of molecules in the space.  Enantiomers are the molecules that are non-superimposable on one another.

The number of possible stereoisomers is calculated as 2n where n is the number of asymmetric carbons present in a compound.

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The SN 1 mechanism starts with the rate-determining step which is the dissociation of the alkyl halide into a carbocation and a halide ion. The next step is the rapid reaction of the carbocation intermediate with the nucleophile; this step completes the nucleophilic substitution stage. The step that follows the nucleophilic substitution is a fast acid-base reaction. The nucleophile now acts as a base to remove the proton from the oxonium ion from the previous step, to give the observed product. Draw a curved arrow mechanism for the reaction, adding steps as necessary. Be sure to include all nonzero formal charges. Cl: Add/Remove step G Click and drag to start drawing a structure.

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