
General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Question
Chapter 20, Problem 41P
Interpretation Introduction
(1)
Interpretation:
Hemiacetal carbon of the given aldopentoses needs to be labeled.
Concept introduction:
Hemiacetal carbon is a carbon atom bonded to both an alcohol group and an ether group.
Interpretation Introduction
(2)
Interpretation:
The given monosaccharide needs to be classified as β or a.
Concept introduction:
β or a monosaccharides are named according to the position of the hydroxyl group in the anomeric carbon atom. If the OH group is on the right hand side, the monosaccharide will be β and if it is on the left hand side, the monosaccharide will be a.
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Part A
Identify each alcohol as primary, secondary, or tertiary
Drag the appropriate items to their respective bins.
CH₂
H₂C-
-C-OH
HO
CH₂
Primary
Он
OH
CH₂
OH
CCH₂OH
CH₂
сн
Secondary
Tertiary
Reset Help
CH,CH₂
(CH)CHCH,OH CH,CH,CH,CCH,
CHOH
CH₂
Different types of alcohol groups
Alcohol and its reaction:
8. Combing two alcohol molecules below and completing the reaction with
Product .( Hint Reaction called etherification as ether is formed and name the
ether once you complete the reaction.
Hint.:
R-O-H+H-O-RR-O-R
Do the reaction:
CH₂OH + CH₂OH---→
+ H-O-H
9. Write the reaction of formation of alcohol from alkene by adding water:
Addition reaction also called hydration reaction as we are adding water
which occur always in presence of acid
Hint: Break the double bond and add H and OH if symmetrical then
add anywhere if unsymmetrical then follow Markovnikov rule H
should go to that double bone carbon which has more hydrogen
CH2=CH2 + H₂O-→
Complete the reaction
hand written please
Predict the major products of this organic reaction:
HBr (1 equiv)
cold
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
dm
Re
Explanation
Check
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Chapter 20 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 20.1 - Label the hemiacetal carbonthe carbon bonded to...Ch. 20.2 - Prob. 20.1PPCh. 20.2 - Prob. 20.2PCh. 20.2 - Prob. 20.3PCh. 20.2 - Prob. 20.4PCh. 20.2 - Prob. 20.5PCh. 20.2 - Prob. 20.2PPCh. 20.2 - Prob. 20.6PCh. 20.2 - Prob. 20.7PCh. 20.3 - Prob. 20.8P
Ch. 20.3 - Prob. 20.3PPCh. 20.3 - Prob. 20.4PPCh. 20.4 - Prob. 20.5PPCh. 20.4 - Prob. 20.6PPCh. 20.4 - Prob. 20.9PCh. 20.4 - Prob. 20.10PCh. 20.5 - Prob. 20.7PPCh. 20.5 - Prob. 20.8PPCh. 20.5 - Lactose contains both an acetal and a hemiacetal....Ch. 20.5 - Prob. 20.12PCh. 20.5 - Prob. 20.13PCh. 20.5 - Prob. 20.14PCh. 20.5 - Prob. 20.15PCh. 20.6 - Prob. 20.16PCh. 20.6 - Prob. 20.17PCh. 20.7 - Prob. 20.18PCh. 20.7 - Prob. 20.19PCh. 20.8 - Prob. 20.20PCh. 20 - Prob. 21PCh. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Prob. 24PCh. 20 - Prob. 25PCh. 20 - Prob. 26PCh. 20 - Prob. 27PCh. 20 - Prob. 28PCh. 20 - Prob. 29PCh. 20 - Prob. 30PCh. 20 - Prob. 31PCh. 20 - Prob. 32PCh. 20 - Prob. 33PCh. 20 - Prob. 34PCh. 20 - Prob. 35PCh. 20 - Prob. 36PCh. 20 - Prob. 37PCh. 20 - Prob. 38PCh. 20 - Prob. 39PCh. 20 - Prob. 40PCh. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Prob. 43PCh. 20 - Prob. 44PCh. 20 - Prob. 45PCh. 20 - Prob. 46PCh. 20 - What product is formed when each compound is...Ch. 20 - What product is formed when each compound is...Ch. 20 - Prob. 49PCh. 20 - Prob. 50PCh. 20 - Prob. 51PCh. 20 - Prob. 52PCh. 20 - Prob. 53PCh. 20 - Prob. 54PCh. 20 - Prob. 55PCh. 20 - Prob. 56PCh. 20 - Prob. 57PCh. 20 - Prob. 58PCh. 20 - Prob. 59PCh. 20 - Prob. 60PCh. 20 - Prob. 61PCh. 20 - Prob. 62PCh. 20 - Prob. 63PCh. 20 - Prob. 64PCh. 20 - Prob. 65PCh. 20 - Prob. 66PCh. 20 - Prob. 67PCh. 20 - Prob. 68PCh. 20 - Prob. 69PCh. 20 - Prob. 70PCh. 20 - Prob. 71PCh. 20 - Prob. 72PCh. 20 - Prob. 73PCh. 20 - Prob. 74PCh. 20 - Prob. 75PCh. 20 - Prob. 76PCh. 20 - Prob. 77PCh. 20 - Prob. 78PCh. 20 - Prob. 79CPCh. 20 - Prob. 80CP
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